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Received: 2005-05-08

Revision Accepted: 2005-06-28

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Journal of Zhejiang University SCIENCE B 2005 Vol.6 No.8 P.722~724

http://doi.org/10.1631/jzus.2005.B0722


Photochemical reactions of poly(3-butoxythiophene-2,5-diyl) with chloroform


Author(s):  IMIT Mokhtar, YAMAMOTO Takakazu, IMIN Patigul

Affiliation(s):  School of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China; more

Corresponding email(s):   mokhtarjan@sohu.com, tyamamot@res.titech.ac.jp

Key Words:  Poly(3-butoxythiophene-2, 5-diyl), Photochemical reaction, Kinetics


IMIT Mokhtar, YAMAMOTO Takakazu, IMIN Patigul. Photochemical reactions of poly(3-butoxythiophene-2,5-diyl) with chloroform[J]. Journal of Zhejiang University Science B, 2005, 6(8): 722~724.

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author="IMIT Mokhtar, YAMAMOTO Takakazu, IMIN Patigul",
journal="Journal of Zhejiang University Science B",
volume="6",
number="8",
pages="722~724",
year="2005",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.2005.B0722"
}

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%T Photochemical reactions of poly(3-butoxythiophene-2,5-diyl) with chloroform
%A IMIT Mokhtar
%A YAMAMOTO Takakazu
%A IMIN Patigul
%J Journal of Zhejiang University SCIENCE B
%V 6
%N 8
%P 722~724
%@ 1673-1581
%D 2005
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.2005.B0722

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T1 - Photochemical reactions of poly(3-butoxythiophene-2,5-diyl) with chloroform
A1 - IMIT Mokhtar
A1 - YAMAMOTO Takakazu
A1 - IMIN Patigul
J0 - Journal of Zhejiang University Science B
VL - 6
IS - 8
SP - 722
EP - 724
%@ 1673-1581
Y1 - 2005
PB - Zhejiang University Press & Springer
ER -
DOI - 10.1631/jzus.2005.B0722


Abstract: 
photochemical reactions of poly(3-butoxythiophene-2,5-diyl) with chloroform under irradiation with light were studied. The reactions were separately carried out under air, oxygen, and nitrogen. The obtained results showed that this reaction belongs to the pseudo-first-order reaction with a rate constant kobs of 1.4×10−5 s−1 at room temperature. The presence or absence of air, oxygen, and nitrogen did not have obvious effects on the reaction rate under irradiation with light.

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Reference

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