Full Text:   <30707>

CLC number: X506

On-line Access: 2009-04-05

Received: 2008-07-09

Revision Accepted: 2008-10-28

Crosschecked: 2009-03-04

Cited: 417

Clicked: 8256

Citations:  Bibtex RefMan EndNote GB/T7714

-   Go to

Article info.
1. Reference List
Open peer comments

Journal of Zhejiang University SCIENCE A 2009 Vol.10 No.5 P.716~724

http://doi.org/10.1631/jzus.A0820524


Critical review in adsorption kinetic models


Author(s):  Hui QIU, Lu LV, Bing-cai PAN, Qing-jian ZHANG, Wei-ming ZHANG, Quan-xing ZHANG

Affiliation(s):  State Key Laboratory of Pollution Control and Resource Reuse, Department of Environmental Engineering, School of the Environment, Nanjing University, Nanjing 210093, China

Corresponding email(s):   bcpan@nju.edu.cn

Key Words:  Adsorption kinetics, Reaction models, Diffusion models, Film diffusion, Intraparticle diffusion


Hui QIU, Lu LV, Bing-cai PAN, Qing-jian ZHANG, Wei-ming ZHANG, Quan-xing ZHANG. Critical review in adsorption kinetic models[J]. Journal of Zhejiang University Science A, 2009, 10(5): 716~724.

@article{title="Critical review in adsorption kinetic models",
author="Hui QIU, Lu LV, Bing-cai PAN, Qing-jian ZHANG, Wei-ming ZHANG, Quan-xing ZHANG",
journal="Journal of Zhejiang University Science A",
volume="10",
number="5",
pages="716~724",
year="2009",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.A0820524"
}

%0 Journal Article
%T Critical review in adsorption kinetic models
%A Hui QIU
%A Lu LV
%A Bing-cai PAN
%A Qing-jian ZHANG
%A Wei-ming ZHANG
%A Quan-xing ZHANG
%J Journal of Zhejiang University SCIENCE A
%V 10
%N 5
%P 716~724
%@ 1673-565X
%D 2009
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.A0820524

TY - JOUR
T1 - Critical review in adsorption kinetic models
A1 - Hui QIU
A1 - Lu LV
A1 - Bing-cai PAN
A1 - Qing-jian ZHANG
A1 - Wei-ming ZHANG
A1 - Quan-xing ZHANG
J0 - Journal of Zhejiang University Science A
VL - 10
IS - 5
SP - 716
EP - 724
%@ 1673-565X
Y1 - 2009
PB - Zhejiang University Press & Springer
ER -
DOI - 10.1631/jzus.A0820524


Abstract: 
Adsorption is one of the most widely applied techniques for environmental remediation. Its kinetics are of great significance to evaluate the performance of a given adsorbent and gain insight into the underlying mechanisms. There are lots of references available concerning adsorption kinetics, and several mathematic models have been developed to describe adsorption reaction and diffusion processes. However, these models were frequently employed to fit the kinetic data in an unsuitable or improper manner. This is mainly because the boundary conditions of the associated models were, to a considerable extent, ignored for data modeling. Here we reviewed several widely-used adsorption kinetic models and paid more attention to their boundary conditions. We believe that the review is of certain significance and improvement for adsorption kinetic modeling.

Darkslateblue:Affiliate; Royal Blue:Author; Turquoise:Article

Reference

[1] Aksu, Z., Kabasakal, E., 2004. Batch adsorption of 2,4-dichlorophenoxy-acetic acid (2,4-D) from aqueous solution by granular activated carbon. Separation and Purification Technology, 35(3):223-240.

[2] Al-Asheh, S., Banat, F., Masad, A., 2004. Kinetics and equilibrium sorption studies of 4-nitrophenol on pyrolyzed and activated oil shale residue. Environmental Geology, 45(8):1109-1117.

[3] Alkan, M., Demirbaş, Ö., Doğan, M., 2007. Adsorption kinetics and thermodynamics of an anionic dye onto sepiolite. Microporous and Mesoporous Materials, 101(3):388-396.

[4] Anirudhan, T.S., Radhakrishnan, P.G., 2008. Thermodynamics and kinetics of adsorption of Cu(II) from aqueous solutions onto a new cation exchanger derived from tamarind fruit shell. The Journal of Chemical Thermodynamics, 40(4):702-709.

[5] Banat, F., Al-Asheh, S., Makhadmeh, L., 2003. Preparation and examination of activated carbons from date pits impregnated with potassium hydroxide for the removal of methylene blue from aqueous solutions. Adsorption Science and Technology, 21(6):597-606.

[6] Boyd, G.E., Adamson, A.W., Myers, L.S., 1947. The exchange adsorption of ions from aqueous solutions by organic zeolites, II, Kinetics. Journal of the American Chemical Society, 69(11):2836-2848.

[7] Chen, Z., Ma, W., Han, M., 2008. Biosorption of nickel and copper onto treated alga (Undaria pinnatifida): Application of isotherm and kinetic models. Journal of Hazardous Materials, 155(1-2):327-333.

[8] Cheng, W., Wang, S.G., Lu, L., Gong, W.X., Liu, X.W., Gao, B.Y., Zhang, H.Y., 2008. Removal of malachite green (MG) from aqueous solutions by native and heat-treated anaerobic granular sludge. Biochemical Engineering Journal, 39(3):538-546.

[9] Cheng, X.M., 2004. Study on the Treatment and Resource Reuse of Methyl Salycylate Industry Wastewater. MS Thesis, Nanjing University, China, p.39-56 (in Chinese).

[10] Cheung, C.W., Porter, J.F., McKay, G., 2001. Sorption kinetic analysis for the removal of cadmium ions from effluents using bone char. Water Research, 35(3):605-612.

[11] Chien, S.H., Clayton, W.R., 1980. Application of Elovich equation to the kinetics of phosphate release and sorption in soils. Soil Science Society of America Journal, 44:265-268.

[12] Chiron, N., Guilet, R., Deydier, E., 2003. Adsorption of Cu(II) and Pb(II) onto a grafted silica: isotherms and kinetic models. Water Research, 37(13):3079-3086.

[13] Coleman, N.T., McClung, A.C., Moore, D.P., 1956. Formation constants for Cu(II)-peat complexes. Science, 123(3191):330-331.

[14] Cooney, D.O., 1999. Adsorption Design for Wastewater Treatment. Lewis Publishers, Boca Raton.

[15] Crank, J., 1956. Mathematics of Diffusion. Oxford at the Clarendon Press, London, England.

[16] Hamadi, N.K., Swaminathan, S., Chen, X.D., 2004. Adsorption of Paraquat dichloride from aqueous solution by activated carbon derived from used tires. Journal of Hazardous Materials, 112(1-2):133-141.

[17] Hameed, B.H., 2008. Equilibrium and kinetic studies of methyl violet sorption by agricultural waste. Journal of Hazardous Materials, 154(1-3):204-212.

[18] Hameed, B.H., El-Khaiary, M.I., 2008a. Batch removal of malachite green from aqueous solutions by adsorption on oil palm trunk fibre: Equilibrium isotherms and kinetic studies. Journal of Hazardous Materials, 154(1-3):237-244.

[19] Hameed, B.H., El-Khaiary, M.I., 2008b. Sorption kinetics and isotherm studies of a cationic dye using agricultural waste: Broad bean peels. Journal of Hazardous Materials, 154(1-3):639-648.

[20] Hameed, B.H., Mahmoud, D.K., Ahmad, A.L., 2008. Equilibrium modeling and kinetic studies on the adsorption of basic dye by a low-cost adsorbent: Coconut (Cocos nucifera) bunch waste. Journal of Hazardous Materials, 158(1):65-72.

[21] Heimberg, J.A., Wahl, K.J., Singer, I.L., Erdemir, A., 2001. Superlow friction behavior of diamond-like carbon coatings: time and speed effects. Applied Physics Letters, 78(17):2449-2451.

[22] Ho, Y.S., 2004. Citation review of Lagergren kinetic rate equation on adsorption reactions. Scientometrics, 59(1):171-177.

[23] Ho, Y.S., 2006. Review of second-order models for adsorption systems. Journal of Hazardous Materials, 136(3):103-111.

[24] Ho, Y.S., McKay, G., 1998a. A comparison of chemisorption kinetic models applied to pollutant removal on various sorbents. Process Safety and Environmental Protection, 76(4):332-340.

[25] Ho, Y.S., McKay, G., 1998b. Sorption of dye from aqueous solution by peat. Chemical Engineering Journal, 70(2):115-124.

[26] Ho, Y.S., McKay, G., 2000. The kinetics of sorption of divalent metal ions onto sphagnum moss peat. Water Research, 34(3):735-742.

[27] Huang, W.W., Wang, S.B., Zhu, Z.H., Li, L., Yao, X.D., Rudolph, V., Haghseresht, F., 2008. Phosphate removal from wastewater using red mud. Journal of Hazardous Materials, 158(1):35-42.

[28] Jain, A.K., Gupta, V.K., Jain, S., Suhas, 2004. Removal of chlorophenols using industrial wastes. Environmental Science & Technology, 38(4):1195-1200.

[29] Lagergren, S., 1898. About the theory of so-called adsorption of soluble substances. Kungliga Svenska Vetenskapsakademiens. Handlingar, 24(4):1-39.

[30] Lazaridis, N.K., Asouhidou, D.D., 2003. Kinetics of sorptive removal of chromium(VI) from aqueous solutions by calcined Mg-Al-CO3 hydrotalcite. Water Research, 37(12):2875-2882.

[31] Low, M.J.D., 1960. Kinetics of chemisorption of gases on solids. Chemical Reviews, 60(3):267-312.

[32] Mahramanlioglu, M., Kizilcikli, I., Bicer, I.O., 2002. Adsorption of fluoride from aqueous solution by acid treated spent bleaching earth. Journal of Fluorine Chemistry, 115(1):41-47.

[33] Meng, F.W., 2005. Study on a Mathematical Model in Predicting Breakthrough Curves of Fixed-bed Adsorption onto Resin Adsorbent. MS Thesis, Nanjing University, China, p.28-36 (in Chinese).

[34] Min, S.H., Han, J.S., Shin, E.W., Park, J.K., 2004. Improvement of cadmium ion removal by base treatment of juniper fiber. Water Research, 38(5):1289-1295.

[35] Namasivayam, C., Kavitha, D., 2005. Adsorptive removal of 2,4-dichlorophenol from aqueous solution by low-cost carbon from an agricultural solid waste: coconut coir pith. Separation Science and Technology, 39(6):1407-1425.

[36] Pan, B.C., Du, W., Zhang, W.M., Zhang, X., Zhang, Q.R., Pan, B.J., Lu, L., Zhang, Q.X., Chen, J.L., 2007. Improved adsorption of 4-nitrophenol onto a novel hyper-cross-linked polymer. Environmental Science & Technology, 41(14):5057-5062.

[37] Petroni, S.L.G., Pires, M.A.F., Munita, C.S., 2004. Use of radiotracer in adsorption studies of copper on peat. Journal of Radioanalytical and Nuclear Chemistry, 259(2):239-243.

[38] Rosa, S., Laranjeira, M.C.M., Riela, H.G., Fάvere, V.T., 2008. Cross-linked quaternary chitosan as an adsorbent for the removal of the reactive dye from aqueous solutions. Journal of Hazardous Materials, 155(1-2):253-260.

[39] Rudzinski, W., Panczyk, T., 2000. Kinetics of isothermal adsorption on energetically heterogeneous solid surfaces: a new theoretical description based on the statistical rate theory of interfacial transport. Journal of Physical Chemistry, 104(39):9149-9162.

[40] Sağ, Y., Aktay, Y., 2002. Kinetic studies on sorption of Cr(VI) and Cu(II) ions by chitin, chitosan and Rhizopus arrhizus. Biochemical Engineering Journal, 12(2):143-153.

[41] Shin, E.W., Han, J.S., Jang, M., Min, S.H., Park, J.K., Rowell, R.M., 2004. Phosphate adsorption on aluminum-impregnated mesoporous silicates: surface structure and behavior of adsorbents. Environmental Science & Technology, 38(3):912-917.

[42] Slaney, A.J, Bhamidimarri, R., 1998. Adsorption of pentachlorophenol (PCP) by actived carbon in fixed beds: application of homogeneous surface diffusion model. Water Science and Technology, 38(7):227-235.

[43] Sun, Q.Y., Yang, L.Z., 2003. The adsorption of basic dyes from aqueous solution on modified peat-resin particle. Water Research, 37(7):1535-1544.

[44] Tan, I.A.W., Ahmad, A.L., Hameed, B.H., 2008. Adsorption of basic dye on high-surface-area activated carbon prepared from coconut husk: Equilibrium, kinetic and thermodynamic studies. Journal of Hazardous Materials, 154(1-3):337-346.

[45] Tien, C., 2007. Remarks on adsorption manuscripts received and declined: An editorial. Separation and Purification Technology, 54(3):277-278.

[46] Tien, C., 2008. Remarks on adsorption manuscripts revised and declined: An editorial. Journal of Hazardous Materials, 150(1):2-3.

[47] Varshney, K.G., Khan, A.A., Gupta, U., Maheshwari, S.M., 1996. Kinetics of adsorption of phosphamidon on antimony(V) phosphate cation exchanger evaluation of the order of reaction and some physical parameters. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 113(1-2):19-23.

[48] Wan Ngah, W.S., Hanafiah, M.A.K.M., 2008. Adsorption of copper on rubber (Hevea brasiliensis) leaf powder: Kinetic, equilibrium and thermodynamic studies. Biochemical Engineering Journal, 39(3):521-530.

[49] Wang, H.L., Chen, J.L., Zhai, Z.C., 2004. Study on thermodynamics and kinetics of adsorption of p-toluidine from aqueous solution by hypercrosslinked polymeric adsorbents. Environmental Chemistry, 23(2):188-192 (in Chinese).

[50] Wilczak, A., Keinath, T.M., 1993. Kinetics of sorption and desorption of copper(II) and lead(II) on activated carbon. Water Environment Research, 65:238-244.

[51] Xu, G.M., Shi, Z., Deng, J., 2006. Adsorption of antimony on IOCS: kinetics and mechanisms. Acta Scientiae Circumstantiae, 26(4):607-612 (in Chinese).

[52] Yan, G.T., Viraraghavan, T., 2003. Heavy-metal removal from aqueous solution by fungus Mucor rouxii. Water Research, 37(18):4486-4496.

[53] Zeldowitsch, J., 1934. Über den mechanismus der katalytischen oxydation von CO an MnO2. Acta Physicochemical URSS, 1:364-449.

Open peer comments: Debate/Discuss/Question/Opinion

<1>

Please provide your name, email address and a comment





Journal of Zhejiang University-SCIENCE, 38 Zheda Road, Hangzhou 310027, China
Tel: +86-571-87952783; E-mail: cjzhang@zju.edu.cn
Copyright © 2000 - Journal of Zhejiang University-SCIENCE