Full Text:   <2191>

CLC number: X511

On-line Access: 2011-06-07

Received: 2010-07-06

Revision Accepted: 2010-11-26

Crosschecked: 2011-05-24

Cited: 4

Clicked: 3053

Citations:  Bibtex RefMan EndNote GB/T7714

-   Go to

Article info.
1. Reference List
Open peer comments

Journal of Zhejiang University SCIENCE A 2011 Vol.12 No.6 P.461-469

http://doi.org/10.1631/jzus.A1000326


Screening study of transition metal oxide catalysts supported on ceria-modified titania for catalytic oxidation of toluene


Author(s):  Dan-qing Yu, Yue Liu, Zhong-biao Wu

Affiliation(s):  Department of Environmental Engineering, Zhejiang University, Hangzhou 310027, China, Zhejiang Provincial Engineering Research Center of Industrial Boiler & Furnace Flue Gas Pollution Control, Hangzhou 310027, China

Corresponding email(s):   yueliu@zju.edu.cn

Key Words:  Transition metal oxides, CeO2/TiO2, Sol-gel method, Catalytic oxidation, Toluene


Dan-qing Yu, Yue Liu, Zhong-biao Wu. Screening study of transition metal oxide catalysts supported on ceria-modified titania for catalytic oxidation of toluene[J]. Journal of Zhejiang University Science A, 2011, 12(6): 461-469.

@article{title="Screening study of transition metal oxide catalysts supported on ceria-modified titania for catalytic oxidation of toluene",
author="Dan-qing Yu, Yue Liu, Zhong-biao Wu",
journal="Journal of Zhejiang University Science A",
volume="12",
number="6",
pages="461-469",
year="2011",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.A1000326"
}

%0 Journal Article
%T Screening study of transition metal oxide catalysts supported on ceria-modified titania for catalytic oxidation of toluene
%A Dan-qing Yu
%A Yue Liu
%A Zhong-biao Wu
%J Journal of Zhejiang University SCIENCE A
%V 12
%N 6
%P 461-469
%@ 1673-565X
%D 2011
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.A1000326

TY - JOUR
T1 - Screening study of transition metal oxide catalysts supported on ceria-modified titania for catalytic oxidation of toluene
A1 - Dan-qing Yu
A1 - Yue Liu
A1 - Zhong-biao Wu
J0 - Journal of Zhejiang University Science A
VL - 12
IS - 6
SP - 461
EP - 469
%@ 1673-565X
Y1 - 2011
PB - Zhejiang University Press & Springer
ER -
DOI - 10.1631/jzus.A1000326


Abstract: 
Six transition metal oxides were added in ceria-modified titania using a sol-gel method for catalytic oxidation of toluene. An MnOx based catalyst was found to be the most active one, with which toluene could be decomposed completely at 200 ºC. The greatest Mn/Ti and molar ratio of the mobile oxygen to the total oxygen concentration, together with a large surface area and a low reduction peak-starting temperature, would result in its best activity in toluene oxidation.

Darkslateblue:Affiliate; Royal Blue:Author; Turquoise:Article

Reference

[1]Alifanti, M., Florea, M., Cortes-Corberan, V., Endruschat, U., Delmon, B., Parvulescu, V.I., 2006. Effect of LaCoO3 perovskite deposition on ceria-based supports on total oxidation of VOC. Catalysis Today, 112(1-4):169-173.

[2]Alvarez-Merino, M.A., Ribeiro, M.F., Silva, J.M., Carrasco-Marian, F., Maldonado-Hodar, F.J., 2004. Activated carbon and tungsten oxide supported on activated carbon catalysts for toluene catalytic combustion. Environmental Science & Technology, 38(17):4664-4670.

[3]Avgouropoulos, G., Oikonomopoulos, E., Kanistras, D., Ioannides, T., 2006. Complete oxidation of ethanol over alkali-promoted Pt/Al2O3 catalysts. Applied Catalysis B: Environmental, 65(1-2):62-69.

[4]Bertinchamps, F., Gregoire, C., Gaigneaux, E.M., 2006. Systematic investigation of supported transition metal oxide based formulations for the catalytic oxidative elimination of (chloro)-aromatics: Part I: Identification of the optimal main active phases and supports. Applied Catalysis B: Environmental, 66(1-2):1-9.

[5]Blanco, J., Petre, A.L., Yates, M., Martin, M.P., Martn, J.A., Martin-Luengo, M.A., 2007. Tailor-made high porosity VOC oxidation catalysts prepared by a single-step procedure. Applied Catalysis B: Environmental, 73(1-2):128-134.

[6]Dai, Q.G., Wang, X.Y., Lu, G.Z., 2008. Low-temperature catalytic combustion of trichloroethylene over cerium oxide and catalyst deactivation. Applied Catalysis B: Environmental, 81(3-4):192-202.

[7]Delimaris, D., Ioannides, T., 2008. VOC oxidation over MnOx-CeO2 catalysts prepared by a combustion method. Applied Catalysis B: Environmental, 84(1-2):303-312.

[8]Deng, J.G., Zhang, L., Dai, H.X., He, H., Au, C.T., 2008. Strontium-doped lanthanum cobaltite and manganite: highly active catalysts for toluene complete oxidation. Industrial & Engineering Chemistry Research, 47(21):8175-8183.

[9]Giraudon, J.M., Elhachimi, A., Wyrwalski, F., Siffert, S., Aboukais, A., Lamonier, J.F., Leclercq, G., 2007. Studies of the activation process over Pd perovskite-type oxides used for catalytic oxidation of toluene. Applied Catalysis B: Environmental, 75(3-4):157-166.

[10]Gutierrez-Ortiz, J.I., Rivas, B., Lopez-Fonseca, R., Martín, S., Gonzalez-Velasco, J.R., 2007. Structure of Mn-Zr mixed oxides catalysts and their catalytic performance in the gas-phase oxidation of chlorocarbons. Chemosphere, 68(6):1004-1012.

[11]Hinwood, A.L., Rodriguez, C., Runnion, T., Farrar, D., Murray, F., Horton, A., Glass, D., Sheppeard, V., Edwards, J.W., Denison, L., et al., 2007. Risk factors for increased BTEX exposure in four Australian cities. Chemosphere, 66(3):533-541.

[12]Huang, H.F., Liu, Y.Q., Tang, W., Chen, Y.F., 2008. Catalytic activity of nanometer La1−xSrxCoO3 (x=0, 0.2) perovskites towards VOCs combustion. Catalysis Communications, 9(1):55-59.

[13]Jiang, B.Q., Liu, Y., Wu, Z.B., 2009. Low-temperature selective catalytic reduction of NO on MnOx/TiO2 prepared by different methods. Journal of Hazardous Material, 162(1):1249-1254.

[14]Kondo, J.N., Domen, K., 2008. Crystallization of mesoporous metal oxides. Chemical Material, 20(3):835-847.

[15]Krishnamoorthy, S., Rivas, J.A., Amiridi, M.D., 2000. Catalytic oxidation of 1,2-dichlorobenzene over supported transition metal oxides. Journal of Catalysis, 193(2):264-272.

[16]Li, J.J., Xu, X.Y., Jiang, Z., Hao, Z.P., Hu, C., 2005. Nanoporous silica-supported nanometric palladium: synthesis, characterization, and catalytic deep oxidation of benzene. Environmental Science and Technology, 39(5):1319-1323.

[17]Machida, M., Uto, M., Kurogi, D., Kijima, T., 2000. MnOx-CeO2 binary oxides for catalytic NOx sorption at low temperatures. sorptive removal of NOx. Chemical Material, 12(10):3158-3164.

[18]Murugan, B., Ramaswamy, A.V., Srinivas, D., Gopinath, C.S., Ramaswamy, V., 2005. Nature of manganese species in Ce1−xMnxO2−δ solid solutions synthesized by the solution combustion route. Chemical Material, 17(15):3983-3993.

[19]Niu, J.R., Deng, J.G., Liu, W., Zhang, L., Wang, G.Z., Dai, H.X., He, H., Zi, X.H., 2007. Nanosized perovskite-type oxides La1−xSrxMO3−δ (M=Co, Mn; x=0, 0.4) for the catalytic removal of ethylacetate. Catalysis Today, 126(3-4):420-429.

[20]Oliveira, L.C.A., Lago, R.M., Fabris, J.D., Sapag, K., 2008. Catalytic oxidation of aromatic VOCs with Cr or Pd-impregnated Al-pillared bentonite: byproduct formation and deactivation studies. Applied Clay Science, 39(3-4):218-222.

[21]Pecchi, G., Reyes, P., Zamora, R., Cadus, L.E., Fierro, J.L.G., 2008. Surface properties and performance for VOCs combustion of LaFe1−yNiyO3 perovskite oxides. Journal of Solid State Chemistry, 181(4):905-912.

[22]Peluso, M.A., Gambaro, L.A., Pronsato, E., Gazzoli, D., Thomas, H.J., Sambeth, J.E., 2008. Synthesis and catalytic activity of manganese dioxide (type OMS-2) for the abatement of oxygenated VOCs. Catalysis Today, 133-135:487-492.

[23]Qi, G.S., Yang, R.T., Chang, R., 2004. MnOx-CeO2 mixed oxides prepared by co-precipitation for selective catalytic reduction of NO with NH3 at low temperatures. Applied Catalysis B: Environmental, 51(2):93-106.

[24]Ribeiro, M.F., Silva, J.M., Brimaud, S., Antunes, A.P., Silva, E.R., Fernandes, A., Magnoux, P., Murphy, D.M., 2007. Improvement of toluene catalytic combustion by addition of cesium in copper exchanged zeolites. Applied Catalysis B: Environmental, 70(1-4):384-392.

[25]Sinha, A.K., Suzuki, K., 2005. Preparation and characterization of novel mesoporous ceria-titania. Jounal of Physical Chemistry B, 109(5):1708-1714.

[26]Stoyanova, M., Konova, P., Nikolov, P., Naydenov, A., Christoskova, S., Mehandjiev, D., 2006. Alumina- supported nickel oxide for ozone decomposition and catalytic ozonation of CO and VOCs. Chemical Engineering Journal, 122(1-2):41-46.

[27]Tidahy, H.L., Siffert, S., Wyrwalski, F., Lamonier, J.F., Aboukais, A., 2007. Catalytic activity of copper and palladium based catalysts for toluene total oxidation. Catalysis Today, 119(1-4):317-320.

[28]Wang, X.Y., Kang, Q., Li, D., 2009. Catalytic combustion of chlorobenzene over MnOx-CeO2 mixed oxide catalysts. Applied Catalysis B: Environmental, 86(3-4):166-175.

[29]Wu, Z.B., Jiang, B.Q., Liu, Y., Zhao, W.R., Guan, B.H., 2007. Experimental study on a low-temperature SCR catalyst based on MnOx/TiO2 prepared by sol-gel method. Journal of Hazardous Materials, 145(3):488-494.

[30]Wyrwalski, F., Lamonier, J.F., Siffert, S., Aboukais, A., 2007. Additional effects of cobalt precursor and zirconia support modifications for the design of efficient VOC oxidation catalysts. Applied Catalysis B: Environmental, 70(1-4):393-399.

[31]Xu, W.Q., He, H., Yu, Y.B., 2009. Deactivation of a Ce/TiO2 catalyst by SO2 in the selective catalytic reduction of NO by NH3. Journal of Physical Chemistry C, 113(11):4426-4432.

[32]Yu, D.Q., Liu, Y., Wu, Z.B., 2010. Low temperature catalytic oxidation of toluene over mesoporous MnOx-CeO2/TiO2 prepared by sol-gel method. Catalysis Communications, 11(8):788-791.

[33]Yuan, S.H., Shen, M., Gong, M.C., Wang, J.L., Yan, S.H., Cao, H.Y., Chen, Y.Q., 2008. Catalytic combustion of ethyl acetate over Al2O3-Ce0.5Zr0.5O2 supported metal oxide catalysts. Acta Physico-Chimica Sinica, 24(3):364-368.

Open peer comments: Debate/Discuss/Question/Opinion

<1>

Please provide your name, email address and a comment





Journal of Zhejiang University-SCIENCE, 38 Zheda Road, Hangzhou 310027, China
Tel: +86-571-87952783; E-mail: cjzhang@zju.edu.cn
Copyright © 2000 - Journal of Zhejiang University-SCIENCE