CLC number: TQ032.4
On-line Access: 2024-08-27
Received: 2023-10-17
Revision Accepted: 2024-05-08
Crosschecked: 2016-11-24
Cited: 2
Clicked: 4861
Citations: Bibtex RefMan EndNote GB/T7714
Umsa Jameel, Ming-qiao Zhu, Xin-zhi Chen, Yi Liu, Zhang-fa Tong. Green epoxidation of cyclooctene with molecular oxygen over an ecofriendly heterogeneous polyoxometalate-gold catalyst Au/BW11/Al2O3[J]. Journal of Zhejiang University Science A, 2016, 17(12): 1000-1012.
@article{title="Green epoxidation of cyclooctene with molecular oxygen over an ecofriendly heterogeneous polyoxometalate-gold catalyst Au/BW11/Al2O3",
author="Umsa Jameel, Ming-qiao Zhu, Xin-zhi Chen, Yi Liu, Zhang-fa Tong",
journal="Journal of Zhejiang University Science A",
volume="17",
number="12",
pages="1000-1012",
year="2016",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.A1500332"
}
%0 Journal Article
%T Green epoxidation of cyclooctene with molecular oxygen over an ecofriendly heterogeneous polyoxometalate-gold catalyst Au/BW11/Al2O3
%A Umsa Jameel
%A Ming-qiao Zhu
%A Xin-zhi Chen
%A Yi Liu
%A Zhang-fa Tong
%J Journal of Zhejiang University SCIENCE A
%V 17
%N 12
%P 1000-1012
%@ 1673-565X
%D 2016
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.A1500332
TY - JOUR
T1 - Green epoxidation of cyclooctene with molecular oxygen over an ecofriendly heterogeneous polyoxometalate-gold catalyst Au/BW11/Al2O3
A1 - Umsa Jameel
A1 - Ming-qiao Zhu
A1 - Xin-zhi Chen
A1 - Yi Liu
A1 - Zhang-fa Tong
J0 - Journal of Zhejiang University Science A
VL - 17
IS - 12
SP - 1000
EP - 1012
%@ 1673-565X
Y1 - 2016
PB - Zhejiang University Press & Springer
ER -
DOI - 10.1631/jzus.A1500332
Abstract: An ecofriendly heterogeneous polyoxometalate (POM)-gold catalyst Au/BW11/Al2O3 was synthesized and used for solvent-free epoxidation of cyclooctene under mild reaction conditions using molecular oxygen as an oxidant and t-butyl hydroperoxide (TBHP) as an initiator. The catalyst was characterized by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX), X-ray diffraction (XRD), induced coupled plasma optical emission spectrometry (ICP-OES), and Brunauer-Emmett-Teller (BET). The catalyst showed good conversion and high selectivity without use of solvents or environmentally harmful oxidants. Moreover, the catalyst is recyclable up to three cycles with no significant loss in selectivity towards epoxide.
This manuscript describes the synthesis of catalytic system which consisting with nano gold-polyoxometalate catalyst supported on the surface of neutral alumina. The resulting Au/BW11/Al2O3 was very effective for solvent-free epoxidation of cyclooctene under mild reaction conditions using molecular oxygen as an oxidant and TBHP as an initiator.
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