CLC number:
On-line Access: 2024-08-27
Received: 2023-10-17
Revision Accepted: 2024-05-08
Crosschecked: 2023-02-24
Cited: 0
Clicked: 1250
Haiguang ZHANG, Kunlong ZHAO, Qingxi HU, Jinhe WANG. Preparation and 3D printing of high-thermal-conductivity continuous mesophase-pitch-based carbon fiber/epoxy composites[J]. Journal of Zhejiang University Science A, 2023, 24(2): 162-172.
@article{title="Preparation and 3D printing of high-thermal-conductivity continuous mesophase-pitch-based carbon fiber/epoxy composites",
author="Haiguang ZHANG, Kunlong ZHAO, Qingxi HU, Jinhe WANG",
journal="Journal of Zhejiang University Science A",
volume="24",
number="2",
pages="162-172",
year="2023",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.A2200413"
}
%0 Journal Article
%T Preparation and 3D printing of high-thermal-conductivity continuous mesophase-pitch-based carbon fiber/epoxy composites
%A Haiguang ZHANG
%A Kunlong ZHAO
%A Qingxi HU
%A Jinhe WANG
%J Journal of Zhejiang University SCIENCE A
%V 24
%N 2
%P 162-172
%@ 1673-565X
%D 2023
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.A2200413
TY - JOUR
T1 - Preparation and 3D printing of high-thermal-conductivity continuous mesophase-pitch-based carbon fiber/epoxy composites
A1 - Haiguang ZHANG
A1 - Kunlong ZHAO
A1 - Qingxi HU
A1 - Jinhe WANG
J0 - Journal of Zhejiang University Science A
VL - 24
IS - 2
SP - 162
EP - 172
%@ 1673-565X
Y1 - 2023
PB - Zhejiang University Press & Springer
ER -
DOI - 10.1631/jzus.A2200413
Abstract: To meet the requirements of spacecraft for the thermal conductivity of resins and solve the problem of low thermal conduction efficiency when 3D printing complex parts, we propose a new type of continuous mesophase-pitch-based carbon fiber/thermoplastic polyurethane/epoxy (CMPCF/TPU/epoxy) composite filament and its preparation process in this study. The composite filament is based on the high thermal conductivity of CMPCF, the high elasticity of TPU, and the high-temperature resistance of epoxy. The tensile strength and thermal conductivity of the CMPCF/TPU/epoxy composite filament were tested. The CMPCF/TPU/epoxy composites are formed by 3D printing technology, and the composite filament is laid according to the direction of heat conduction so that the printed part can meet the needs of directional heat conduction. The experimental results show that the thermal conductivity of the printed sample is 40.549 W/(m·K), which is 160 times that of pure epoxy resin (0.254 W/(m·K)). It is also approximately 13 times better than that of polyacrylonitrile carbon fiber/epoxy (PAN-CF/epoxy) composites. This study breaks through the technical bottleneck of poor printability of CMPCF. It provides a new method for achieving directional thermal conductivity printing, which is important for the development of complex high-performance thermal conductivity products.
[1]ASTM (American Society for Testing and Materials), 2017. Standard Test Methods for Properties of Continuous Filament Carbon and Graphite Fiber Tows, ASTM D4018-17. American Society for Testing and Materials, USA.
[2]DongKX, ShengN, ZouDQ, et al., 2020. A high-thermal-conductivity, high-durability phase-change composite using a carbon fibre sheet as a supporting matrix. Applied Energy, 264:114685.
[3]FanBH, LiuY, HeDL, et al., 2017. Enhanced thermal conductivity for mesophase pitch-based carbon fiber/modified boron nitride/epoxy composites. Polymer, 122:71-76.
[4]GarimellaSV, PersoonsT, WeibelJA, et al., 2017. Electronics thermal management in information and communications technologies: challenges and future directions. IEEE Transactions on Components, Packaging and Manufacturing Technology, 7(8):1191-1205.
[5]GuoHC, ZhaoHY, NiuHY, et al., 2021. Highly thermally conductive 3D printed graphene filled polymer composites for scalable thermal management applications. ACS Nano, 15(4):6917-6928.
[6]GuoLC, ZhangZY, LiMH, et al., 2020. Extremely high thermal conductivity of carbon fiber/epoxy with synergistic effect of MXenes by freeze-drying. Composites Communications, 19:134-141.
[7]HuJT, HuangY, YaoYM, et al., 2017. Polymer composite with improved thermal conductivity by constructing a hierarchically ordered three-dimensional interconnected network of BN. ACS Applied Materials & Interfaces, 9(15):13544-13553.
[8]IsarnI, BonnaudL, MassaguésL, et al., 2020. Study of the synergistic effect of boron nitride and carbon nanotubes in the improvement of thermal conductivity of epoxy composites. Polymer International, 69(3):280-290.
[9]JiJC, ChiangSW, LiuMJ, et al., 2020. Enhanced thermal conductivity of alumina and carbon fibre filled composites by 3-D printing. Thermochimica Acta, 690:178649.
[10]LiuJC, LiWW, GuoYF, et al., 2019. Improved thermal conductivity of thermoplastic polyurethane via aligned boron nitride platelets assisted by 3D printing. Composites Part A: Applied Science and Manufacturing, 120:140-146.
[11]MaC, MaZ, GaoLH, et al., 2018. Preparation and characterization of coatings with anisotropic thermal conductivity. Materials & Design, 160:1273-1280.
[12]MaJK, ShangTY, RenLL, et al., 2020. Through-plane assembly of carbon fibers into 3D skeleton achieving enhanced thermal conductivity of a thermal interface material. Chemical Engineering Journal, 380:122550.
[13]MingYK, WangB, ZhouJ, et al., 2021. Performance and applications of 3D printed continuous fiber-reinforced thermosetting composites. Aeronautical Manufacturing Technology, 64(15):58-65 (in Chinese).
[14]MirandaAT, BolzoniL, BarekarN, et al., 2018. Processing, structure and thermal conductivity correlation in carbon fibre reinforced aluminium metal matrix composites. Materials & Design, 156:329-339.
[15]MunSY, LimHM, LeeDJ, 2015. Thermal conductivity of a silicon carbide/pitch-based carbon fiber-epoxy composite. Thermochimica Acta, 619:16-19.
[16]NaTY, LiuX, JiangH, et al., 2018. Enhanced thermal conductivity of fluorinated epoxy resins by incorporating inorganic filler. Reactive and Functional Polymers, 128:84-90.
[17]OhH, KimY, KimJ, 2019. Co-curable poly (glycidyl methacrylate)-grafted graphene/epoxy composite for thermal conductivity enhancement. Polymer, 183:121834.
[18]StepashkinАA, ChukovDI, SenatovFS, et al., 2018. 3D-printed PEEK-carbon fiber (CF) composites: structure and thermal properties. Composites Science and Technology, 164:319-326.
[19]TangB, YiM, LiangYM, et al., 2020. Preparation and study on the thermal conductivity of high thermal conductivity pitch based carbon fiber/epoxy composite. China Plastics Industry, 48(8):157-160 (in Chinese).
[20]TarhiniAA, Tehrani-BaghaAR, 2019. Graphene-based polymer composite films with enhanced mechanical properties and ultra-high in-plane thermal conductivity. Composites Science and Technology, 184:107797.
[21]TongYL, TaoZC, LiYF, et al., 2022. Carbon materials with high thermal conductivity and its application in spacecraft. Chinese Space Science and Technology, 42(1):131-138 (in Chinese).
[22]WattsR, KistnerM, CollearyA, 2006. Materials opportunity to electronic composite enclosures for aerospace and spacecraft thermal management. American Institute of Physics, 813(1):19-26.
[23]WuB, LiJJ, LiX, et al., 2021. Gravity driven ice-templated oriental arrangement of functional carbon fibers for high in-plane thermal conductivity. Composites Part A: Applied Science and Manufacturing, 150:106623.
[24]WuWF, LiuN, ChengWL, et al., 2013. Study on the effect of shape-stabilized phase change materials on spacecraft thermal control in extreme thermal environment. Energy Conversion and Management, 69:174-180.
[25]XiaoC, TangYL, ChenL, et al., 2019. Preparation of highly thermally conductive epoxy resin composites via hollow boron nitride microbeads with segregated structure. Composites Part A: Applied Science and Manufacturing, 121:330-340.
[26]XiaoWK, LuoXJ, MaPF, et al., 2018. Structure factors of carbon nanotubes on the thermal conductivity of carbon nanotube/epoxy composites. AIP Advances, 8(3):035107.
[27]XueF, HanX, SunDH, 2015. The application of 3D printing technology in space composites manufacturing. Spacecraft Recovery & Remote Sensing, 36(2):77-82 (in Chinese).
[28]YangW, HuoHL, LiHB, et al., 2020. Research progress of multifunctional thermal control materials and structures of aerospace vehicles. Structure & Environment Engineering, 47(2):1-12 (in Chinese).
[29]ZhengXR, KimS, ParkCW, 2019. Enhancement of thermal conductivity of carbon fiber-reinforced polymer composite with copper and boron nitride particles. Composites Part A: Applied Science and Manufacturing, 121:449-456.
[30]ZhuCY, ChenZH, ZhuRJ, et al., 2021. Vertically aligned Al2O3 fiber framework leading to anisotropically enhanced thermal conductivity of epoxy composites. Advanced Engineering Materials, 23(9):2100327.
Open peer comments: Debate/Discuss/Question/Opinion
<1>