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CLC number: O69

On-line Access: 2012-06-06

Received: 2011-10-31

Revision Accepted: 2012-01-16

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Journal of Zhejiang University SCIENCE B 2012 Vol.13 No.6 P.503-510

http://doi.org/10.1631/jzus.B1100337


Electrocatalytic response of poly(cobalt tetraaminophthalocyanine)/ multi-walled carbon nanotubes-Nafion modified electrode toward sulfadiazine in urine


Author(s):  Xiao-ping Hong, Yan Zhu, Yan-zhen Zhang

Affiliation(s):  Department of Chemistry, Zhejiang University, Hangzhou 310028, China; more

Corresponding email(s):   zyz85@hotmail.com

Key Words:  Sulfadiazine, Electrochemical detection, Cobalt tetraaminophthalocyanine, Multi-walled carbon nanotubes


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Xiao-ping Hong, Yan Zhu, Yan-zhen Zhang. Electrocatalytic response of poly(cobalt tetraaminophthalocyanine)/ multi-walled carbon nanotubes-Nafion modified electrode toward sulfadiazine in urine[J]. Journal of Zhejiang University Science B, 2012, 13(6): 503-510.

@article{title="Electrocatalytic response of poly(cobalt tetraaminophthalocyanine)/ multi-walled carbon nanotubes-Nafion modified electrode toward sulfadiazine in urine",
author="Xiao-ping Hong, Yan Zhu, Yan-zhen Zhang",
journal="Journal of Zhejiang University Science B",
volume="13",
number="6",
pages="503-510",
year="2012",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.B1100337"
}

%0 Journal Article
%T Electrocatalytic response of poly(cobalt tetraaminophthalocyanine)/ multi-walled carbon nanotubes-Nafion modified electrode toward sulfadiazine in urine
%A Xiao-ping Hong
%A Yan Zhu
%A Yan-zhen Zhang
%J Journal of Zhejiang University SCIENCE B
%V 13
%N 6
%P 503-510
%@ 1673-1581
%D 2012
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.B1100337

TY - JOUR
T1 - Electrocatalytic response of poly(cobalt tetraaminophthalocyanine)/ multi-walled carbon nanotubes-Nafion modified electrode toward sulfadiazine in urine
A1 - Xiao-ping Hong
A1 - Yan Zhu
A1 - Yan-zhen Zhang
J0 - Journal of Zhejiang University Science B
VL - 13
IS - 6
SP - 503
EP - 510
%@ 1673-1581
Y1 - 2012
PB - Zhejiang University Press & Springer
ER -
DOI - 10.1631/jzus.B1100337


Abstract: 
A highly sensitive amperometric sulfadiazine sensor fabricated by electrochemical deposition of poly(cobalt tetraaminophthalocyanine) (poly(CoIITAPc)) on the surface of a multi-walled carbon nanotubes-Nafion (MWCNTs-Nafion) modified electrode is described. This electrode showed a very attractive performance by combining the advantages of CoIITAPc, MWCNTs, and Nafion. Compared with the bare glassy carbon electrode (GCE) and the MWCNTs-Nafion modified electrode, the electrocatalytic activity of poly(CoIITAPc)-coated MWCNTs-Nafion GCE generated greatly improved electrochemical detections toward sulfadiazine including low oxidation potential, high current responses, and good anti-fouling performance. The oxidation peak currents of sulfadiazine obtained on the new modified electrode increased linearly while increasing the concentration of sulfadiazine from 0.5 to 43.5 μmol/L with the detection limit of 0.17 μmol/L.

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