CLC number: X52
On-line Access:
Received: 2008-04-12
Revision Accepted: 2008-07-07
Crosschecked: 2008-10-29
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Jing-jing WO, Zhen ZHANG, Xin-hua XU. Dechlorination mechanism of 2,4-dichlorophenol by Ni/Fe nanoparticles in the presence of humic acid[J]. Journal of Zhejiang University Science A, 2009, 10(1): 121-126.
@article{title="Dechlorination mechanism of 2,4-dichlorophenol by Ni/Fe nanoparticles in the presence of humic acid",
author="Jing-jing WO, Zhen ZHANG, Xin-hua XU",
journal="Journal of Zhejiang University Science A",
volume="10",
number="1",
pages="121-126",
year="2009",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.A0820277"
}
%0 Journal Article
%T Dechlorination mechanism of 2,4-dichlorophenol by Ni/Fe nanoparticles in the presence of humic acid
%A Jing-jing WO
%A Zhen ZHANG
%A Xin-hua XU
%J Journal of Zhejiang University SCIENCE A
%V 10
%N 1
%P 121-126
%@ 1673-565X
%D 2009
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.A0820277
TY - JOUR
T1 - Dechlorination mechanism of 2,4-dichlorophenol by Ni/Fe nanoparticles in the presence of humic acid
A1 - Jing-jing WO
A1 - Zhen ZHANG
A1 - Xin-hua XU
J0 - Journal of Zhejiang University Science A
VL - 10
IS - 1
SP - 121
EP - 126
%@ 1673-565X
Y1 - 2009
PB - Zhejiang University Press & Springer
ER -
DOI - 10.1631/jzus.A0820277
Abstract: To understand the feasibility of its application to the in situ remediation of contaminated groundwater, the 28dechlorination%29&ck%5B%5D=abstract&ck%5B%5D=keyword'>2f4a8b>dechlorination of 2,4-dichlorophenol (2,4-DCP) by 28ni/Fe nanoparticles%29&ck%5B%5D=abstract&ck%5B%5D=keyword'>2f4a8b>ni/Fe nanoparticles in the presence of humic acid (HA) was investigated. We found that, as high performance liquid chromatography (HPLC) was used, the 2,4-DCP was first quickly reduced to o-chlorophenol (o-CP) and p-chlorophenol (p-CP), and then reduced to phenol as the final product. Our experimental results indicated that HA had an adverse effect on the 28dechlorination%29&ck%5B%5D=abstract&ck%5B%5D=keyword'>2f4a8b>dechlorination of 2,4-DCP by 28ni/Fe nanoparticles%29&ck%5B%5D=abstract&ck%5B%5D=keyword'>2f4a8b>ni/Fe nanoparticles, as the HA concentration increased, the removal rate decreased evidently. It also demonstrated that 2,4-DCP was reduced more easily to o-CP than to p-CP, and that the sequence of the tendency in 28dechlorination%29&ck%5B%5D=abstract&ck%5B%5D=keyword'>2f4a8b>dechlorination of intermediates was p-CP>o-CP. Transmission electron microscope (TEM) showed that HA could act as an adsorbate to compete reactive sites on the surface of 28ni/Fe nanoparticles%29&ck%5B%5D=abstract&ck%5B%5D=keyword'>2f4a8b>ni/Fe nanoparticles to decrease the 28dechlorination%29&ck%5B%5D=abstract&ck%5B%5D=keyword'>2f4a8b>dechlorination rate. Also we concluded that the 28dechlorination%29&ck%5B%5D=abstract&ck%5B%5D=keyword'>2f4a8b>dechlorination reaction of 2,4-DCP over 28ni/Fe nanoparticles%29&ck%5B%5D=abstract&ck%5B%5D=keyword'>2f4a8b>ni/Fe nanoparticles progressed through catalytic reductive 28dechlorination%29&ck%5B%5D=abstract&ck%5B%5D=keyword'>2f4a8b>dechlorination.
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