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CLC number: O69

On-line Access: 2016-02-02

Received: 2015-07-22

Revision Accepted: 2015-10-08

Crosschecked: 2016-01-25

Cited: 1

Clicked: 1349

Citations:  Bibtex RefMan EndNote GB/T7714

 ORCID:

Hao-jie Yu

http://orcid.org/0000-0002-7405-7881

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Journal of Zhejiang University SCIENCE A 2016 Vol.17 No.2 P.144-154

http://doi.org/10.1631/jzus.A1500183


Synthesis of ferrocene- and azobenzene-based compounds for anion recognition


Author(s):  Xiao-ting Zhai, Hao-jie Yu, Li Wang, Zheng Deng, Zain-ul Abdin, Yong-sheng Chen

Affiliation(s):  The State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China

Corresponding email(s):   hjyu@zju.edu.cn, opl_wl@dial.zju.edu.cn

Key Words:  Ferrocene, Azobenzene, Hydrogen bonding, High density information storage, Anion recognition


Xiao-ting Zhai, Hao-jie Yu, Li Wang, Zheng Deng, Zain-ul Abdin, Yong-sheng Chen. Synthesis of ferrocene- and azobenzene-based compounds for anion recognition[J]. Journal of Zhejiang University Science A, 2016, 17(2): 144-154.

@article{title="Synthesis of ferrocene- and azobenzene-based compounds for anion recognition",
author="Xiao-ting Zhai, Hao-jie Yu, Li Wang, Zheng Deng, Zain-ul Abdin, Yong-sheng Chen",
journal="Journal of Zhejiang University Science A",
volume="17",
number="2",
pages="144-154",
year="2016",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.A1500183"
}

%0 Journal Article
%T Synthesis of ferrocene- and azobenzene-based compounds for anion recognition
%A Xiao-ting Zhai
%A Hao-jie Yu
%A Li Wang
%A Zheng Deng
%A Zain-ul Abdin
%A Yong-sheng Chen
%J Journal of Zhejiang University SCIENCE A
%V 17
%N 2
%P 144-154
%@ 1673-565X
%D 2016
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.A1500183

TY - JOUR
T1 - Synthesis of ferrocene- and azobenzene-based compounds for anion recognition
A1 - Xiao-ting Zhai
A1 - Hao-jie Yu
A1 - Li Wang
A1 - Zheng Deng
A1 - Zain-ul Abdin
A1 - Yong-sheng Chen
J0 - Journal of Zhejiang University Science A
VL - 17
IS - 2
SP - 144
EP - 154
%@ 1673-565X
Y1 - 2016
PB - Zhejiang University Press & Springer
ER -
DOI - 10.1631/jzus.A1500183


Abstract: 
A series of ferrocene- and azobenzene-based compounds with acyl amine groups attached were designed and synthesized to explore their potential application in anion recognition. Their electro- and photo-properties, and the effect of nitro and amine substituents of the benzene ring on anion recognition were studied by UV-vis absorption spectroscopy (UV) and cyclic voltammetry (CV). The results showed that a nitro group substituent has a positive effect on the binding affinity and sensitivity, which might be due to the strong hydrogen bonding interaction between the receptor and the guest, while an amino group substituent has a negative effect on the sensitivity. Furthermore, the shift in the UV-vis absorption spectra was observed as a color change, which can be used for the naked-eye detection of F and H2PO4.

This paper describes the design, preparation and anion recognition property study of three ferrocene and azobenzene based compounds. While the synthesis is simple and straightforward, the resulting compounds showed promising and interesting selective recognition of anions. I think this article nicely describes the design and synthesis of ferrocene chromophore system and evaluate the products as potential ion detectors. I thought the synthesis was presented in a fashion that is not in the traditional synthetic experimental style where the produce for all new compounds are presented followed by a list of the spectral data (e.g., Rf, mp, IR, 1H NMR, 13CNMR and HRMS) for new all new compounds.

用于阴离子识别的二茂铁基偶氮苯化合物的合成

目的:研究二茂铁基偶氮苯化合物的光电响应性能及 离子识别性能,并研究取代基对其离子识别性能的影响。
创新点:考察取代基对于二茂铁基偶氮苯化合物的影响,并提出可能的机理。
方法:循环伏安(CV)法和紫外可见吸收光谱(UV-vis)法。
结论:通过CV法和UV-vis法研究二茂铁基偶氮苯化合物的离子识别性能,发现硝基取代的化合物对于F-和H2PO4-具有选择性离子识别作用,而氨基取代的化合物则识别作用不明显。

关键词:二茂铁;偶氮苯;光电响应;离子识别

Darkslateblue:Affiliate; Royal Blue:Author; Turquoise:Article

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