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Journal of Zhejiang University SCIENCE B 2013 Vol.14 No.7 P.650-658

http://doi.org/10.1631/jzus.B12a0225


Adsorption of methylene blue onto activated carbon produced from tea (Camellia sinensis L.) seed shells: kinetics, equilibrium, and thermodynamics studies


Author(s):  Jun-jie Gao, Ye-bo Qin, Tao Zhou, Dong-dong Cao, Ping Xu, Danielle Hochstetter, Yue-fei Wang

Affiliation(s):  Department of Tea Science, Zhejiang University, Hangzhou 310058, China; more

Corresponding email(s):   zdxp@zju.edu.cn, tyfwang@gmail.com

Key Words:  Activated carbon, Adsorption, Tea seed shells, Methylene blue


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Jun-jie Gao, Ye-bo Qin, Tao Zhou, Dong-dong Cao, Ping Xu, Danielle Hochstetter, Yue-fei Wang. Adsorption of methylene blue onto activated carbon produced from tea (Camellia sinensis L.) seed shells: kinetics, equilibrium, and thermodynamics studies[J]. Journal of Zhejiang University Science B, 2013, 14(7): 650-658.

@article{title="Adsorption of methylene blue onto activated carbon produced from tea (Camellia sinensis L.) seed shells: kinetics, equilibrium, and thermodynamics studies",
author="Jun-jie Gao, Ye-bo Qin, Tao Zhou, Dong-dong Cao, Ping Xu, Danielle Hochstetter, Yue-fei Wang",
journal="Journal of Zhejiang University Science B",
volume="14",
number="7",
pages="650-658",
year="2013",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.B12a0225"
}

%0 Journal Article
%T Adsorption of methylene blue onto activated carbon produced from tea (Camellia sinensis L.) seed shells: kinetics, equilibrium, and thermodynamics studies
%A Jun-jie Gao
%A Ye-bo Qin
%A Tao Zhou
%A Dong-dong Cao
%A Ping Xu
%A Danielle Hochstetter
%A Yue-fei Wang
%J Journal of Zhejiang University SCIENCE B
%V 14
%N 7
%P 650-658
%@ 1673-1581
%D 2013
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.B12a0225

TY - JOUR
T1 - Adsorption of methylene blue onto activated carbon produced from tea (Camellia sinensis L.) seed shells: kinetics, equilibrium, and thermodynamics studies
A1 - Jun-jie Gao
A1 - Ye-bo Qin
A1 - Tao Zhou
A1 - Dong-dong Cao
A1 - Ping Xu
A1 - Danielle Hochstetter
A1 - Yue-fei Wang
J0 - Journal of Zhejiang University Science B
VL - 14
IS - 7
SP - 650
EP - 658
%@ 1673-1581
Y1 - 2013
PB - Zhejiang University Press & Springer
ER -
DOI - 10.1631/jzus.B12a0225


Abstract: 
Tea (Camellia sinensis L.) seed shells, the main byproduct of the manufacture of tea seed oil, were used as precursors for the preparation of tea activated carbon (TAC) in the present study. A high yield (44.1%) of TAC was obtained from tea seed shells via a one-step chemical method using ZnCl2 as an agent. The Brunauer-Emmett-Teller (BET) surface area and the total pore volumes of the obtained TAC were found to be 1530.67 mg2/g and 0.7826 cm3/g, respectively. The equilibrium adsorption results were complied with Langmuir isotherm model and its maximum monolayer adsorption capacity was 324.7 mg/g for methylene blue. adsorption kinetics studies indicated that the pseudo-second-order model yielded the best fit for the kinetic data. An intraparticle diffusion model suggested that the intraparticle diffusion was not the only rate-controlling step. Thermodynamics studies revealed the spontaneous and exothermic nature of the sorption process. These results indicate that tea seed shells could be utilized as a renewable resource to develop activated carbon which is a potential adsorbent for methylene blue.

Darkslateblue:Affiliate; Royal Blue:Author; Turquoise:Article

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