JZUS - Journal of Zhejiang University SCIENCE

Journal of Zhejiang University SCIENCE A

Accepted manuscript available online (unedited version)

Occurrence of the Bunsen side reaction in the sulfur-iodine thermochemical cycle for hydrogen production

Author(s): Qiao-qiao Zhu, Yan-wei Zhang, Zhi Ying, Jun-hu Zhou, Zhi-hua Wang, Ke-fa Cen
Affiliation(s): . State Key Laboratory of Clean Energy Utilization, Department of Energy Engineering, Zhejiang University, Hangzhou 310027, China
Corresponding email(s): zhangyw@zju.edu.cn
Key Words: Thermochemical sulfur-iodine cycle, Hydrogen production, Side reaction, Sulfur, Hydrogen sulfide

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Qiao-qiao Zhu, Yan-wei Zhang, Zhi Ying, Jun-hu Zhou, Zhi-hua Wang, Ke-fa Cen. Occurrence of the Bunsen side reaction in the sulfur-iodine thermochemical cycle for hydrogen production[J]. Journal of Zhejiang University Science A,in press.Frontiers of Information Technology & Electronic Engineering,in press.https://doi.org/10.1631/jzus.A1200313

@article{title="Occurrence of the Bunsen side reaction in the sulfur-iodine thermochemical cycle for hydrogen production",
author="Qiao-qiao Zhu, Yan-wei Zhang, Zhi Ying, Jun-hu Zhou, Zhi-hua Wang, Ke-fa Cen",
journal="Journal of Zhejiang University Science A",
year="in press",
publisher="Zhejiang University Press & Springer",
doi="https://doi.org/10.1631/jzus.A1200313"
}

%0 Journal Article
%T Occurrence of the Bunsen side reaction in the sulfur-iodine thermochemical cycle for hydrogen production
%A Qiao-qiao Zhu
%A Yan-wei Zhang
%A Zhi Ying
%A Jun-hu Zhou
%A Zhi-hua Wang
%A Ke-fa Cen
%J Journal of Zhejiang University SCIENCE A
%P 300-306
%@ 1673-565X
%D in press
%I Zhejiang University Press & Springer
doi="https://doi.org/10.1631/jzus.A1200313"

TY - JOUR
T1 - Occurrence of the Bunsen side reaction in the sulfur-iodine thermochemical cycle for hydrogen production
A1 - Qiao-qiao Zhu
A1 - Yan-wei Zhang
A1 - Zhi Ying
A1 - Jun-hu Zhou
A1 - Zhi-hua Wang
A1 - Ke-fa Cen
J0 - Journal of Zhejiang University Science A
SP - 300
EP - 306
%@ 1673-565X
Y1 - in press
PB - Zhejiang University Press & Springer
ER -
doi="https://doi.org/10.1631/jzus.A1200313"

Abstract
Chinese Summary
Academic Network
Reviewer Comment

Abstract: This study aimed to establish a closed-cycle operation technology with high thermal efficiency in the sulfur-iodine cycle"&ck%5B%5D=abstract&ck%5B%5D=keyword'>thermochemical sulfur-iodine cycle for large-scale hydrogen production. A series of experimental studies were performed to investigate the occurrence of side reactions in both the H₂SO₄ and HI _x phases from the H₂SO₄/HI/I₂/H₂O quaternary system within a constant temperature range of 323–363 K. The effects of iodine content, water content and reaction temperature on the side reactions were evaluated. The results showed that an increase in the reaction temperature promoted the side reactions. However, they were prevented as the iodine or water content increased. The occurrence of side reactions was faster in kinetics and more intense in the H₂SO₄ phase than in the HI _x phase. The sulfur or hydrogen sulfide formation reaction or the reverse Bunsen reaction was validated under certain conditions.

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References