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On-line Access: 2023-10-18
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Haoliang WU, Heng SONG, Xinpo SUN, Yuzhang BI, Shenjing FU, Ning YANG. Geo-environmental properties and microstructural characteristics of sustainable limestone calcined clay cement (LC3) binder treated Zn-contaminated soils[J]. Journal of Zhejiang University Science A,in press.Frontiers of Information Technology & Electronic Engineering,in press.https://doi.org/10.1631/jzus.A2200531 @article{title="Geo-environmental properties and microstructural characteristics of sustainable limestone calcined clay cement (LC3) binder treated Zn-contaminated soils", %0 Journal Article TY - JOUR
可持续石灰石煅烧粘土水泥(LC3)固化剂处理锌污染土的环境岩土特性及微观结构特征机构:1中山大学,土木工程学院,广东省海洋土木工程重点实验室,中国广州,510275,中国;2南方海洋科学与工程广东省实验室(珠海),中国珠海,519082;3四川轻化工大学,土木工程学院,中国自贡,643002;4东南大学,交通学院,中国南京,211189 目的:传统水泥材料普通硅酸盐水泥(OPC)处置总金属污染土面临高碳排及长期环境安全性的问题。本文旨在利用新型低碳探讨多尺度的形式获取新型绿色低碳固化剂石灰石煅烧粘土水泥(LC3)修复锌污染土的关键环境岩土工程参数,揭示LC3固化稳定化锌污染土的微观机理。 创新点:1.探明LC3固化多浓度梯度Zn污染土的物理化学特性、力学强度和环境安全性特征规律;2.揭示LC3固化土重金属固定及强度增长的关键机理。 方法:1.通过无侧限抗压强度(UCS)和渗透试验,获取LC3固化多浓度梯度Zn污染土的力学参数发展规律(图3);2.通过毒性特征浸出试验(TCLP)和合成沉降浸出试验(SPLP),得到LC3固化剂符合毒性浸出安全指标的浓度(图6);3.采用X射线衍射(XRD)、扫描电子显微镜-能谱仪(SEM-EDS)等微观测试技术,明确LC3固化Zn污染土的微观机理(图7和8)。 结论:1.证明了LC3替代OPC处理锌污染土壤的可行性;2.LC3和OPC固化污染土的UCS和渗透率k之间为负增长关系;3.LC3固化土壤中的锌离子及提高污染土强度的主要取决于水化产物的形成。 关键词组: Darkslateblue:Affiliate; Royal Blue:Author; Turquoise:Article
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