CLC number:
On-line Access: 2023-10-18
Received: 2023-02-15
Revision Accepted: 2023-05-15
Crosschecked: 2023-10-19
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Jinchi SUN, Xiongwei TIAN, Zhangqing LIU, Jie SUN, Menglian ZHENG. Microfluidic fuel cells integrating slanted groove micro-mixers to terminate growth of depletion boundary layer thickness[J]. Journal of Zhejiang University Science A,in press.Frontiers of Information Technology & Electronic Engineering,in press.https://doi.org/10.1631/jzus.A2300087 @article{title="Microfluidic fuel cells integrating slanted groove micro-mixers to terminate growth of depletion boundary layer thickness", %0 Journal Article TY - JOUR
集成斜槽微混合器以终止耗尽边界层厚度增长的微流体燃料电池机构:1浙江大学,能源工程学院,热工与动力系统研究所,中国杭州,310027;2浙大宁波理工学院,能源与环境工程研究所,中国宁波,315100;3能源高效清洁利用全国重点实验室,中国杭州,310027 目的:由于微流体燃料电池通常在共层流状态下运行以实现无膜设计,因此它们通常在扩散传输方面受到严重的传质限制。本文旨在研究新型流道设计并提供优化设计的一般性理论模型。 创新点:1.提出了在流道侧壁集成斜槽微混合器的新型微流体燃料电池,并发现了其耗尽边界层厚度停止增长的现象;2.针对存在横向二次流的传质过程开发了简化的模型以及极限电流密度的无量纲关系式。 方法:1.通过计算流体力学软件模拟新型流道中电解质的传质过程,研究预测电池性能(极限电流密度与氧化剂流和燃料流之间的对流混合);2.通过开发简化的模型,揭示横向二次流的传质强化机理;3.通过推导无量纲关系式,分析设计参数对极限电流密度的影响。 结论:1.与无槽微流体燃料电池相比,集成斜槽微混合器的微流体燃料电池实现了显著的传质增强,且极限电流密度增加了115%;2.由于电解质之间界面附近的横向二次流动较弱,所以电解质之间的对流混合得到了很好的控制;3.研究发现耗尽边界层厚度的增长在距离通道入口仅10倍流道高度处终止,并可用简化的传质模型进行机理解释;4.无量纲关系式表明,随着电极长度的增加,极限电流密度具有渐近值,且该数值受电极附近横向流动速度以及电极宽度的显著影响。 关键词组: Darkslateblue:Affiliate; Royal Blue:Author; Turquoise:Article
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