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Solvent effects on hydrogen bonding between primary alcohols and esters
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DHARMALINGAM K., RAMACHANDRAN K., SIVAGURUNATHAN P.. Solvent effects on hydrogen bonding between primary alcohols and esters[J]. Journal of Zhejiang University Science A, 2006, 7(11): 1928-1931.
@article{title="Solvent effects on hydrogen bonding between primary alcohols and esters",
author="DHARMALINGAM K., RAMACHANDRAN K., SIVAGURUNATHAN P.",
journal="Journal of Zhejiang University Science A",
volume="7",
number="11",
pages="1928-1931",
year="2006",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.2006.A1928"
}
%0 Journal Article
%T Solvent effects on hydrogen bonding between primary alcohols and esters
%A DHARMALINGAM K.
%A RAMACHANDRAN K.
%A SIVAGURUNATHAN P.
%J Journal of Zhejiang University SCIENCE A
%V 7
%N 11
%P 1928-1931
%@ 1673-565X
%D 2006
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.2006.A1928
TY - JOUR
T1 - Solvent effects on hydrogen bonding between primary alcohols and esters
A1 - DHARMALINGAM K.
A1 - RAMACHANDRAN K.
A1 - SIVAGURUNATHAN P.
J0 - Journal of Zhejiang University Science A
VL - 7
IS - 11
SP - 1928
EP - 1931
%@ 1673-565X
Y1 - 2006
PB - Zhejiang University Press & Springer
ER -
DOI - 10.1631/jzus.2006.A1928
Abstract: The interaction by hydrogen bond formation of some primary alcohols (1-heptanol, 1-octanol and 1-decanol) with esters (methyl methacrylate, ethyl methacrylate and butyl methacrylate) was investigated in non-polar solvents viz., n-heptane, CCl4 and benzene by means of FTIR spectroscopy. Formation constants and free energy changes of complex formation were determined. The dependence of the equilibrium constants and free energy changes of complex formation on the alkyl chain length of both the alcohols and esters are discussed. The solvent effect on the hydrogen bond formation is discussed in terms of specific interaction between the solute and solvent.
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