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Journal of Zhejiang University SCIENCE A 2004 Vol.5 No.5 P.603~608

http://doi.org/10.1631/jzus.2004.0603


Study of transport behavior for Fe-doping La0.67Ca0.33MnO3 perovskite manganese


Author(s):  CUI Yu-jian, GE Hong-liang, HAN Yan-bing, JIA Guang-qiang, WANG Xin-yan, CAO Yi-gang, ZHANG Jin-cang

Affiliation(s):  Department of Physics, China Institute of Metrology, Hangzhou 310018, China; more

Corresponding email(s):   yjcui@cim.edu.cn

Key Words:  La2/3Ca1/3MnO3, Fe-doping, Crystal structure, Transport properties


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CUI Yu-jian, GE Hong-liang, HAN Yan-bing, JIA Guang-qiang, WANG Xin-yan, CAO Yi-gang, ZHANG Jin-cang. Study of transport behavior for Fe-doping La0.67Ca0.33MnO3 perovskite manganese[J]. Journal of Zhejiang University Science A, 2004, 5(5): 603~608.

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author="CUI Yu-jian, GE Hong-liang, HAN Yan-bing, JIA Guang-qiang, WANG Xin-yan, CAO Yi-gang, ZHANG Jin-cang",
journal="Journal of Zhejiang University Science A",
volume="5",
number="5",
pages="603~608",
year="2004",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.2004.0603"
}

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%T Study of transport behavior for Fe-doping La0.67Ca0.33MnO3 perovskite manganese
%A CUI Yu-jian
%A GE Hong-liang
%A HAN Yan-bing
%A JIA Guang-qiang
%A WANG Xin-yan
%A CAO Yi-gang
%A ZHANG Jin-cang
%J Journal of Zhejiang University SCIENCE A
%V 5
%N 5
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%@ 1869-1951
%D 2004
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.2004.0603

TY - JOUR
T1 - Study of transport behavior for Fe-doping La0.67Ca0.33MnO3 perovskite manganese
A1 - CUI Yu-jian
A1 - GE Hong-liang
A1 - HAN Yan-bing
A1 - JIA Guang-qiang
A1 - WANG Xin-yan
A1 - CAO Yi-gang
A1 - ZHANG Jin-cang
J0 - Journal of Zhejiang University Science A
VL - 5
IS - 5
SP - 603
EP - 608
%@ 1869-1951
Y1 - 2004
PB - Zhejiang University Press & Springer
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DOI - 10.1631/jzus.2004.0603


Abstract: 
Systematic studies of the transport properties of La0.67Ca0.33Mn1-xFexO3 (x=0-0.3) systems showed that with increasing fe-doping content x the resistance increases and the insulator-metal transition temperature moves to lower temperature. For small doping content, the transport property satisfies metal transport behavior below the transition temperature, and above the transition temperature it satisfies the small polaron model. This behavior can be explained by Fe3+ doping, which easily forms Fe3+-O2--Mn4+ channel, suppressing the double exchange Mn3+-O2--Mn4+ channel and enhancing the spin scattering of Mn ions induced by antiferromagnetic clusters of Fe ions.

Darkslateblue:Affiliate; Royal Blue:Author; Turquoise:Article

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