Full Text:   <2127>

CLC number: X703

On-line Access: 

Received: 2006-02-20

Revision Accepted: 2006-07-10

Crosschecked: 0000-00-00

Cited: 42

Clicked: 5450

Citations:  Bibtex RefMan EndNote GB/T7714

-   Go to

Article info.
1. Reference List
Open peer comments

Journal of Zhejiang University SCIENCE A 2006 Vol.7 No.11 P.1928~1931

http://doi.org/10.1631/jzus.2006.A1928


Solvent effects on hydrogen bonding between primary alcohols and esters


Author(s):  DHARMALINGAM K., RAMACHANDRAN K., SIVAGURUNATHAN P.

Affiliation(s):  Department of Physics, Annamalai University, Annamalai Nagar, 608002, Tamilnadu, India

Corresponding email(s):   sivatamil2001@rediffmail.com

Key Words:  FTIR spectroscopy, Primary alcohols, Esters, Hydrogen bonding, Solvent effect


DHARMALINGAM K., RAMACHANDRAN K., SIVAGURUNATHAN P.. Solvent effects on hydrogen bonding between primary alcohols and esters[J]. Journal of Zhejiang University Science A, 2006, 7(11): 1928~1931.

@article{title="Solvent effects on hydrogen bonding between primary alcohols and esters",
author="DHARMALINGAM K., RAMACHANDRAN K., SIVAGURUNATHAN P.",
journal="Journal of Zhejiang University Science A",
volume="7",
number="11",
pages="1928~1931",
year="2006",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.2006.A1928"
}

%0 Journal Article
%T Solvent effects on hydrogen bonding between primary alcohols and esters
%A DHARMALINGAM K.
%A RAMACHANDRAN K.
%A SIVAGURUNATHAN P.
%J Journal of Zhejiang University SCIENCE A
%V 7
%N 11
%P 1928~1931
%@ 1673-565X
%D 2006
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.2006.A1928

TY - JOUR
T1 - Solvent effects on hydrogen bonding between primary alcohols and esters
A1 - DHARMALINGAM K.
A1 - RAMACHANDRAN K.
A1 - SIVAGURUNATHAN P.
J0 - Journal of Zhejiang University Science A
VL - 7
IS - 11
SP - 1928
EP - 1931
%@ 1673-565X
Y1 - 2006
PB - Zhejiang University Press & Springer
ER -
DOI - 10.1631/jzus.2006.A1928


Abstract: 
The interaction by hydrogen bond formation of some primary alcohols (1-heptanol, 1-octanol and 1-decanol) with esters (methyl methacrylate, ethyl methacrylate and butyl methacrylate) was investigated in non-polar solvents viz., n-heptane, CCl4 and benzene by means of FTIR spectroscopy. Formation constants and free energy changes of complex formation were determined. The dependence of the equilibrium constants and free energy changes of complex formation on the alkyl chain length of both the alcohols and esters are discussed. The solvent effect on the hydrogen bond formation is discussed in terms of specific interaction between the solute and solvent.

Darkslateblue:Affiliate; Royal Blue:Author; Turquoise:Article

Reference

[1] Dharmalingam, K., Ramachandran, K., 2006. Solvent effects on hydrogen bonding between 1-pentanol and butyl methacrylate. Phys. Chem. Liq., 44(1):77-81.

[2] Dharmalingam, K., Ramachandran, K., Sivagurunathan, P., 2005. Hydrogen bonding interaction between ethyl methacrylate and alcohols in non-polar solvents: an FTIR study. Main Group Chemistry, 4(3):241-246.

[3] Dharmalingam, K., Ramachandran, K., Sivagurunathan, P., 2006a. FTIR study of molecular interaction in butyl methacrylate-organic solvents mixtures. Z. Phys. Chem., 220:739-748.

[4] Dharmalingam, K., Ramachandran, K., Sivagurunathan, P., 2006b. Hydrogen bonding interaction between acrylic esters and monohydric alcohols in non-polar solvents: an FTIR study. Spectrochim. Acta A (in Press).

[5] Nash, C.P., 1960. The calculation of equilibrium constants from spectro-photometric data. J. Phys. Chem., 64:950-953.

[6] Savage, P.E., 1999. Organic chemical reactions in supercritical water. Chem. Rev., 99(2):603.

[7] Schildknecht, C.E., 1997. Vinyl and Related Polymers. Wiley, New York.

[8] Sivagurunathan, P., Dharmalingam, K., Ramachandran, K., 2005a. Molecular interaction studies of acrylic esters with alcohols. Indian J. Pure Appl. Phys., 43:905-910.

[9] Sivagurunathan, P., Dharmalingam, K., Ramachandran, K., 2005b. Molecular interaction studies of n-propanol with methyl methacrylate in inert solvents. Indian J. Phys., 79:1403-1405.

[10] Sivagurunathan, P., Dharmalingam, K., Ramachandran, K., 2005c. Solvent effects on hydrogen bonding between ethyl methacrylate and 1-butanol. Z. Phys. Chem., 219:1385-1390.

[11] Sivagurunathan, P., Dharmalingam, K., Ramachandran, K., 2005d. Hydrogen bonding interaction between methyl methacrylate and alcohols. Z. Phys. Chem., 219:1635-1638.

[12] Sivagurunathan, P., Dharmalingam, K., Ramachandran, K., Kalamse, G.M., 2005e. Molecular association of alkyl methacrylates and alcohols in non-polar solvents─Dielectric study. Main Group Chemistry, 4(3):227-234.

[13] Sivagurunathan, P., Dharmalingam, K., Ramachandran, K., 2006a. Molecular interaction studies of acrylic esters with 1-alcohols. Spectrochim. Acta, 64A:127-129.

[14] Sivagurunathan, P., Dharmalingam, K., Ramachandran, K., Prabhakar Undre, B., Khirade, P.W., Mehrotra, S.C., 2006b. Dielectric study of butyl methacrylate-alcohol mixtures by Time Domain Reflectometry. Physica B (in Press).

[15] Sivagurunathan, P., Dharmalingam, K., Ramachandran, K., Prabhakar Undre, B., Khirade, P.W., Mehrotra, S.C., 2006c. Dielectric relaxation study of alkyl methacrylates+1-alcohols mixtures using time domain reflectometry. Phil. Mag. Lett., 86(5):291-300.

[16] Vinogradov, C.R.H., 1971. Hydrogen Bonding. Van Nostrand Reinhold Company, New York.

[17] Vogal, A.I., 1957. Text Book of Practical Organic Chemistry (3rd Ed.). Longman, London.

Open peer comments: Debate/Discuss/Question/Opinion

<1>

Please provide your name, email address and a comment





Journal of Zhejiang University-SCIENCE, 38 Zheda Road, Hangzhou 310027, China
Tel: +86-571-87952783; E-mail: cjzhang@zju.edu.cn
Copyright © 2000 - Journal of Zhejiang University-SCIENCE