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 ORCID:

Bate BATE

https://orcid.org/0000-0002-8692-8402

Danting ZHANG

https://orcid.org/0009-0004-0360-8932

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Journal of Zhejiang University SCIENCE A 2024 Vol.25 No.9 P.749-762

http://doi.org/10.1631/jzus.A2300372


Chemical oxygen demand oxidation via sustained-release persulfate balls: a rate-compatibility study of flow velocity, releasing, and oxidation


Author(s):  Bate BATE, Danting ZHANG, Jianshe YE, Min XIA, Yixin YANG, Shuai ZHANG

Affiliation(s):  Institute of Geotechnical Engineering, Zhejiang University, Hangzhou 310058, China; more

Corresponding email(s):   delphinezhangdanting@gmail.com

Key Words:  Chemical oxygen demand (COD), Sodium persulfate (PS), Sustained-release balls, Permeable reactive barrier (PRB), Fe(II)‍, -loaded activated carbon (Fe-AC)


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Bate BATE, Danting ZHANG, Jianshe YE, Min XIA, Yixin YANG, Shuai ZHANG. Chemical oxygen demand oxidation via sustained-release persulfate balls: a rate-compatibility study of flow velocity, releasing, and oxidation[J]. Journal of Zhejiang University Science A, 2024, 25(9): 749-762.

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author="Bate BATE, Danting ZHANG, Jianshe YE, Min XIA, Yixin YANG, Shuai ZHANG",
journal="Journal of Zhejiang University Science A",
volume="25",
number="9",
pages="749-762",
year="2024",
publisher="Zhejiang University Press & Springer",
doi="10.1631/jzus.A2300372"
}

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%T Chemical oxygen demand oxidation via sustained-release persulfate balls: a rate-compatibility study of flow velocity, releasing, and oxidation
%A Bate BATE
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A1 - Min XIA
A1 - Yixin YANG
A1 - Shuai ZHANG
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DOI - 10.1631/jzus.A2300372


Abstract: 
Identification of chemical oxygen demand (COD) in municipal solid waste (MSW) landfill leachates is a challenging problem. This paper investigated the feasibility of using sodium persulfate (PS), a strong oxidant, as a permeable reactive barrier (PRB) filling material. Firstly, sustained-release persulfate balls were manufactured to adjust the release rate of persulfate, the oxidation agent. In addition, fe(II)‍;-loaded activated carbon (Fe-AC) was used to help with an even distribution of Fe(II) in the porous medium (PRB in this case). Then, the oxidation efficiency and kinetic rate of COD removal by the sustained-release balls were subjected to batch tests. A mass ratio of 1׃1.4׃0.24׃0.7 for PS:cement׃sand׃water was the most efficient for COD removal (95%). The breakthrough curve for a 5 mm sustained-release ball revealed that the retardation factor was 1.27 and that the hydrodynamic dispersion coefficient was 15.6 cm2/d. The corresponding half-life of COD oxidation was 0.43 d, which was comparable with the half-life of PS release from sustained-release balls (0.56 d). The sustained-release persulfate balls were shown to be an economical material with a simple recipe and production method when catalyzed by Fe-AC. Compared with cutting-edge methods, sustained-release balls used in PRBs offer significant advantages in terms of both effectiveness and economy for the preparation of sustained-release and catalytic materials. These results verified the feasibility of using sustained-release persulfate balls as a PRB material for COD removal.

过硫酸钠缓释球氧化COD的渗流、释放和氧化速率协调研究

作者:巴特1,章丹婷2,叶建设3,夏敏4,杨一鑫1,张帅1
机构:1浙江大学,岩土工程研究所,中国杭州,310058;2上海环联生态科技有限公司,中国上海,201106;3中铁二院华东勘察设计有限责任公司,中国杭州,310043;4浙江大学建筑设计研究院有限公司,中国杭州,310027
目的:本文旨在通过将过硫酸钠制成缓释球,通过反应动力学相关的数据,研究过硫酸钠缓释球作为填充材料在可渗透反应墙中的可行性及相关参数。
创新点:1.通过合适的配比制备过硫酸钠缓释球,并获取过硫酸钠的最佳释放速率;2.在不同催化条件下,研究不同粒径过硫酸钠缓释球对化学需氧量(COD)的去除速率。
方法:1.研究活性炭和二价铁负载活性炭等不同催化剂对过硫酸钠去除COD效率的影响;2.研究不同粒径过硫酸钠缓释球过硫酸钠的反应速率;3.研究过硫酸钠缓释球在可渗透反应墙模拟柱实验中对COD的击穿实验。
结论:1.二价铁负载活性炭?过硫酸钠缓释球和过硫酸钠?COD最初的最佳投加量为12?1和12.24?1时,COD的去除率可高达95%。2.过硫酸钠缓释球的释放速率在配比一定的情况下与球直径的线性比例为k=544.6/D;直径为5 mm的过硫酸钠缓释球与COD的氧化速率证明了过硫酸钠缓释球的释放速率和COD反应动力学的氧化速率的一致性。3.过硫酸钠缓释球上的孔隙和裂纹影响了过硫酸钠对COD的去除效率,但反应仍遵循准一级反应动力学。4.二价铁负载活性炭催化过硫酸钠缓释球作为可渗透反应墙中的填充材料,与其他新型碳基材料相比,可解决过硫酸钠在去除COD中的有效性问题,表现出了较高的COD去除效率。

关键词:化学需氧量;过硫酸钠;缓释球;可渗透反应墙;铁基活性炭

Darkslateblue:Affiliate; Royal Blue:Author; Turquoise:Article

Reference

[1]AbdullahB, IlyasS, TahirD, 2018. Nanocomposites Fe/activated carbon/PVA for microwave absorber: synthesis and characterization. Journal of Nanomaterials, 2018:9823263.

[2]Barroso-BogeatA, Alexandre-FrancoM, Fernández-GonzálezC, et al., 2019. Activated carbon surface chemistry: changes upon impregnation with Al(III), Fe(III) and Zn(II)‍- metal oxide catalyst precursors from NO3- aqueous solutions. Arabian Journal of Chemistry, 12(8):3963-3976.

[3]BudaniaR, DangayachS, 2023. A comprehensive review on permeable reactive barrier for the remediation of groundwater contamination. Journal of Environmental Management, 332:117343.

[4]ChenFY, YangY, ChangM, et al., 2013. Release performance and mechanism of the slow-released persulfate materials. Research of Environmental Sciences, 26(9):‍995-1000 (in Chinese).

[5]CEN (Comité Européen de Normalisation), 2004. Leaching Characteristics of Moulded or Monolithic Building and Waste Materials. Determination of Leaching of Inorganic Components with the Diffusion Test. The Tank Test, EA NEN 7375. CEN.

[6]ChengS, ZhangLB, XiaHY, et al., 2016. Ultrasound and microwave-assisted preparation of Fe-activated carbon as an effective low-cost adsorbent for dyes wastewater treatment. RSC Advances, 6(82):78936-78946.

[7]CliftonCL, HuieRE, 1989. Rate constants for hydrogen abstraction reactions of the sulfate radical, SO4-· alcohols. International Journal of Chemical Kinetics, 21(8):677-687.

[8]DasK, KendallC, IsabelleM, et al., 2008. FTIR of touch imprint cytology: a novel tissue diagnostic technique. Journal of Photochemistry and Photobiology B: Biology, 92(3):160-164.

[9]DongB, ZhangRZ, GanYD, et al., 2019. Multiple methods for the identification of heavy metal sources in cropland soils from a resource-based region. Science of The Total Environment, 651:3127-3138.

[10]DongCD, ChenCW, HungCM, 2019. Persulfate activation with rice husk-based magnetic biochar for degrading PAEs in marine sediments. Environmental Science and Pollution Research, 26(33):33781-33790.

[11]DumontG, RobertT, MarckN, et al., 2017. Assessment of multiple geophysical techniques for the characterization of municipal waste deposit sites. Journal of Applied Geophysics, 145:74-83.

[12]FengMB, QuRJ, ZhangXL, et al., 2015. Degradation of flumequine in aqueous solution by persulfate activated with common methods and polyhydroquinone-coated magnetite/multiwalled carbon nanotubes catalysts. Water Research, 85:1-10.

[13]GongYN, LiDL, LuoCZ, et al., 2017. Highly porous graphitic biomass carbon as advanced electrode materials for supercapacitors. Green Chemistry, 19(17):4132-4140.

[14]GoyalH, TyagiT, MondalP, 2023. Life cycle analysis and economic evaluation of adsorptive removal of arsenic from groundwater using GAC and GAC-Fe adsorbents. Journal of Cleaner Production, 429:139557.

[15]GuoX, 2013. Advanced Treatment of Papermaking Wastewater by Sulfate Radical-Based Advanced Oxidation Process. MS Thesis, South China University of Technology, Guangzhou, China(in Chinese).

[16]HanZY, MaHN, ShiGZ, et al., 2016. A review of groundwater contamination near municipal solid waste landfill sites in China. Science of The Total Environment, 569-570:1255-1264.

[17]HussainI, LiMY, ZhangYQ, et al., 2017. Insights into the mechanism of persulfate activation with nZVI/BC nanocomposite for the degradation of nonylphenol. Chemical Engineering Journal, 311:163-172.

[18]KalarubanM, LoganathanP, NguyenTV, et al., 2019. Iron-impregnated granular activated carbon for arsenic removal: application to practical column filters. Journal of Environmental Management, 239:235-243.

[19]KamarajM, SrinivasanNR, AssefaG, et al., 2020. Facile development of sunlit ZnO nanoparticles-activated carbon hybrid from pernicious weed as an operative nano-adsorbent for removal of methylene blue and chromium from aqueous solution: extended application in tannery industrial wastewater. Environmental Technology & Innovation, 17:100540.

[20]KangN, HuaI, RaoPSC, 2004. Production and characterization of encapsulated potassium permanganate for sustained release as an in situ oxidant. Industrial & Engineering Chemistry Research, 43(17):5187-5193.

[21]KhursanSL, Semes’koDG, SafiullinRL, 2006. Quantum-chemical modeling of the detachment of hydrogen atoms by the sulfate radical anion. Russian Journal of Physical Chemistry, 80(3):366-371.

[22]KossonDS, van der SlootHA, EighmyTT, 1996. An approach for estimation of contaminant release during utilization and disposal of municipal waste combustion residues. Journal of Hazardous Materials, 47(1-3):43-75.

[23]KrishnanKA, HaridasA, 2008. Removal of phosphate from aqueous solutions and sewage using natural and surface modified coir pith. Journal of Hazardous Materials, 152(2):527-535.

[24]LeeES, SchwartzFW, 2007. Characteristics and applications of controlled-release KMnO4 for groundwater remediation. Chemosphere, 66(11):2058-2066.

[25]LeeES, GuptaN, 2014. Development and characterization of colloidal silica-based slow-release permanganate gel (SRP-G): laboratory investigations. Chemosphere, 109:195-201.

[26]LeeYC, LiYF, ChenMJ, et al., 2020. Efficient decomposition of perfluorooctanic acid by persulfate with iron-modified activated carbon. Water Research, 174:115618.

[27]LiHY, 2018. Investigation of Typical Organics for Activate Persulfate Degradation. MS Thesis, China University of Petroleum (Beijing), Beijing, China(in Chinese).

[28]LiJ, YangZH, XuHY, et al., 2016. Electrochemical treatment of mature landfill leachate using Ti/RuO2–IrO2 and Al electrode: optimization and mechanism. RSC Advances, 6(53):47509-47519.

[29]LiZ, 2016. Cranular Activated Carbon Supported Iron as a Heterogeneous Persufate Catalyst for the Pretreatment of Mature Landfill Leachate. MS Thesis, Donghua University, Shanghai, China(in Chinese).

[30]LiZJ, YangQ, ZhongY, et al., 2016. Granular activated carbon supported iron as a heterogeneous persulfate catalyst for the pretreatment of mature landfill leachate. RSC Advances, 6(2):987-994.

[31]LiangSH, KaoCM, KuoYC, et al., 2011. In situ oxidation of petroleum-hydrocarbon contaminated groundwater using passive ISCO system. Water Research, 45(8):2496-2506.

[32]LinCW, WuCH, TangCT, et al., 2012. Novel oxygen-releasing immobilized cell beads for bioremediation of BTEX-contaminated water. Bioresource Technology, 124:45-51.

[33]MaHR, ZhangX, FengGQ, et al., 2023a. Carbon nanotube membrane armed with confined iron for peroxymonosulfate activation towards efficient tetracycline removal. Separation and Purification Technology, 312:123319.

[34]MaHR, XuS, ZhangX, et al., 2023b. N-doped coal-based carbon membrane coupling peroxymonosulfate activation for bisphenol a degradation: the role of micro-carbon structure and nitrogen species. Journal of Cleaner Production, 423:138713.

[35]MehrabiN, SoleimaniM, YeganehMM, et al., 2015. Parameter optimization for nitrate removal from water using activated carbon and composite of activated carbon and Fe2O3 nanoparticles. RSC Advances, 5(64):51470-51482.

[36]NetaP, MadhavanV, ZemelH, et al., 1977. Rate constants and mechanism of reaction of sulfate radical anion with aromatic compounds. Journal of the American Chemical Society, 99(1):163-164.

[37]OmoikeAI, HarmonD, 2019. Slow-releasing permanganate ions from permanganate core-manganese oxide shell particles for the oxidative degradation of an algae odorant in water. Chemosphere, 223:391-398.

[38]PadmajaS, AlfassiZB, NetaP, et al., 1993. Rate constants for reactions of SO4- radicals in acetonitrile. International Journal of Chemical Kinetics, 25(3):193-198.

[39]RauscherL, SakulthaewC, ComfortS, 2012. Using slow-release permanganate candles to remediate PAH-contaminated water. Journal of Hazardous Materials, 241-242:441-449.

[40]RossC, MurdochLC, FreedmanDL, et al., 2005. Characteristics of potassium permanganate encapsulated in polymer. Journal of Environmental Engineering, 131(8):1203-1211.

[41]SakulthaewC, ChokejaroenratC, 2016. Oxidation of 17β‍- estradiol in water by slow-release permanganate candles. Environmental Engineering Science, 33(4):224-234.

[42]SinghR, ChakmaS, BirkeV, 2023. Performance of field-scale permeable reactive barriers: an overview on potentials and possible implications for in-situ groundwater remediation applications. Science of the Total Environment, 858:158838.

[43]SongXL, WangC, LiuMQ, et al., 2018. Advanced treatment of biologically treated coking wastewater by persulfate oxidation with magnetic activated carbon composite as a catalyst. Water Science and Technology, 77(7):1891-1898.

[44]TianWJ, ZhangHY, QianZ, et al., 2018. Bread-making synthesis of hierarchically Co@C nanoarchitecture in heteroatom doped porous carbons for oxidative degradation of emerging contaminants. Applied Catalysis B: Environmental, 225:76-83.

[45]TsitonakiA, PetriB, CrimiM, et al., 2010. In situ chemical oxidation of contaminated soil and groundwater using persulfate: a review. Critical Reviews in Environmental Science and Technology, 40(1):55-91.

[46]VeerakumarP, MuthuselvamIP, HungCT, et al., 2016. Biomass-derived activated carbon supported Fe3O4 nanoparticles as recyclable catalysts for reduction of nitroarenes. ACS Sustainable Chemistry & Engineering, 4(12):‍6772-6782.

[47]WangB, ZhangYZ, GaoCY, et al., 2023. Developing novel persulfate pellets to remediate BTEXs-contaminated groundwater. Journal of Water Process Engineering, 52:103505.

[48]WangJ, 2017. Study on Treatment of Refractory Organic Wastewater by Persulfate Activated by Iron Based Sludge-Derived Biochar. PhD Thesis, Huazhong University of Science and Technology, Wuhan, China(in Chinese).

[49]WangZ, LuYS, WuZL, et al., 2014. Study on the interference of persulfate in the process of COD determination and its elimination. Industrial Water Treatment, 34(8):‍78-81 (in Chinese).

[50]XuXY, ZengGM, PengYR, et al., 2012. Potassium persulfate promoted catalytic wet oxidation of fulvic acid as a model organic compound in landfill leachate with activated carbon. Chemical Engineering Journal, 200-202:25-31.

[51]YangJ, 2016. Study on Advanced Treatment of Landfill Leachate by Persulfate. MS Thesis, China University of Geosciences (Beijing), Beijing, China(in Chinese).

[52]YangS, OostromM, TruexMJ, et al., 2016. Injectable silica-permanganate gel as a slow-release MnO4- source for groundwater remediation: rheological properties and release dynamics. Environmental Science: Processes & Impacts, 18(2):256-264.

[53]YaoYJ, ChenH, QinJC, et al., 2016. Iron encapsulated in boron and nitrogen codoped carbon nanotubes as synergistic catalysts for fenton-like reaction. Water Research, 101:281-291.

[54]YeJS, ChenX, ChenC, et al., 2019. Emerging sustainable technologies for remediation of soils and groundwater in a municipal solid waste landfill site‍–‍a review. Chemosphere, 227:681-702.

[55]ZengXL, HuangYZ, ZhangY, et al., 2017. Elimination of persulfate interference in determination of COD in organic wastewater. Journal of Chongqing University, 40(12):79-86 (in Chinese).

[56]ZhangL, TuLY, LiangY, et al., 2018. Coconut-based activated carbon fibers for efficient adsorption of various organic dyes. RSC Advances, 8(74):42280-42291.

[57]ZhangXL, FengMB, QuRJ, et al., 2016. Catalytic degradation of diethyl phthalate in aqueous solution by persulfate activated with nano-scaled magnetic CuFe2O4/MWCNTs. Chemical Engineering Journal, 301:1-11.

[58]ZhaoJJ, SunYJ, ZhangY, et al., 2021. Heterogeneous activation of persulfate by activated carbon supported iron for efficient amoxicillin degradation. Environmental Technology & Innovation, 21:101259.

[59]ZhaoJJ, SunYJ, ZhangBT, et al., 2023. Amoxicillin degradation in the heat, light, or heterogeneous catalyst activated persulfate systems: comparison of kinetics, mechanisms and toxicities. Journal of Environmental Management, 348:119386.

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