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Received: 2007-01-25

Revision Accepted: 2007-05-14

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Journal of Zhejiang University SCIENCE A 2007 Vol.8 No.9 P.1462~1468


Investigating the potential of using acoustic frequency on the degradation of linear alkylbenzen sulfonates from aqueous solution

Author(s):  DEHGHANI Mohammad Hadi, MAHVI Amir Hossein, NAJAFPOOR Ali Asghar, AZAM Kamal

Affiliation(s):  Department of Environmental Health Engineering, School of Public Health, Center for Environmental Research, Medical Sciences/University of Tehran, Tehran, I.R. Iran; more

Corresponding email(s):   mohadehghani@yahoo.com

Key Words:  Acoustical reactor, Linear alkylbenzen sulfonate (LAS), Acoustic frequency, Treatment time, Power

DEHGHANI Mohammad Hadi, MAHVI Amir Hossein, NAJAFPOOR Ali Asghar, AZAM Kamal. Investigating the potential of using acoustic frequency on the degradation of linear alkylbenzen sulfonates from aqueous solution[J]. Journal of Zhejiang University Science A, 2007, 8(9): 1462~1468.

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author="DEHGHANI Mohammad Hadi, MAHVI Amir Hossein, NAJAFPOOR Ali Asghar, AZAM Kamal",
journal="Journal of Zhejiang University Science A",
publisher="Zhejiang University Press & Springer",

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%T Investigating the potential of using acoustic frequency on the degradation of linear alkylbenzen sulfonates from aqueous solution
%A DEHGHANI Mohammad Hadi
%A MAHVI Amir Hossein
%A AZAM Kamal
%J Journal of Zhejiang University SCIENCE A
%V 8
%N 9
%P 1462~1468
%@ 1673-565X
%D 2007
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.2007.A1462

T1 - Investigating the potential of using acoustic frequency on the degradation of linear alkylbenzen sulfonates from aqueous solution
A1 - DEHGHANI Mohammad Hadi
A1 - MAHVI Amir Hossein
A1 - NAJAFPOOR Ali Asghar
A1 - AZAM Kamal
J0 - Journal of Zhejiang University Science A
VL - 8
IS - 9
SP - 1462
EP - 1468
%@ 1673-565X
Y1 - 2007
PB - Zhejiang University Press & Springer
ER -
DOI - 10.1631/jzus.2007.A1462

The effectiveness of using acoustical (sonochemical) reactor for degradation of linear alkylbenzen sulfonate (LAS) from aqueous solution was investigated. LASs are anionic surfactants, found in relatively high amounts in domestic and industrial wastewaters. In this study, experiments on LAS solution were performed using methylene blue active substances (MBAS) method. The effectiveness of acoustical processor reactor for LAS degradation is evaluated with emphasis on the effect of treatment time and initial LAS concentration. Experiments were performed at initial concentrations of 0.2, 0.5, 0.8 and 1.0 mg/L, acoustic frequency of 130 kHz, applied power of 500 W and temperature of 18 °C~20 °C. At the conditions involved, LAS degradation was found to increase with increasing sonochemical time. In addition, as the concentration increased, the LAS degradation rate decreased in the acoustical processor reactor.

Darkslateblue:Affiliate; Royal Blue:Author; Turquoise:Article


[1] Abd-Allah, A.M.A., 1995. Determination of long-chain alkylbenzenes in the sediment samples from Alexandria Coast, Egypt. Toxicol. Environ. Chem., 47:83-88.

[2] Adachi, A.D., Karnide, M., Kawafune, R., Miki, N., Kobayashi, T., 1990. Removal efficiency of anionic and non-ionic surfactants from chemical wastewater by treatment plant using activated carbon adsorption and coagulation precipitation processes. Environ. Technol., 11:133-140.

[3] APHA (American Public Health Association), 2005. Standard Methods for the Examination of Water and Wastewater (17th Ed.). American Public Health Association, Washington, DC.

[4] ARCRCP (Australian Research Council’s Research Centers Program), 2005. Polymer Chemistry Glossary. Key Center for Polymer Colloids.

[5] Baleux, B.A., Caumette, P., 1977. Biodegradation of some cationic surfactants. Water Res., 11(9):833-841.

[6] Baskaran, P., Gopalakrishnasany, G., Sathiyabana, P., 1991. Impact of commercial detergent (Nirma) on feeding energetics and protein metabolism in the water teleost fish, Oreochromis mossambicus. Eototoxicol. Environ. Monit., 1:31-40.

[7] Beltrán, F.J., García-Araya, J.F., Álvarez, P.M., 2000. Sodium dodecylbenzenesulfonate removal from water and wastewater. 1. Kinetics of decomposition by ozonation. Ind. Eng. Chem. Res., 39(7):2214-2220.

[8] Brillas, E., Bastida, R.M., Llosa, E., Casado, J., 1995. Electrochemical destruction of aniline and 4-chloroaniline for wastewater treatment using a carbon-PTFE O2-fed cathode. Journal of the Electrochemical Society, 142(6):1733-1741.

[9] Comninellis, C., 1994. Electrocatalysis in the electrochemical conversion/combustion of organic pollutants for wastewater treatment. Electrochimica Acta, 39(11-12):1857-1862.

[10] Crum, L.A., Mason, T.J., Reisse, J., Suslick, K.S., 1999. Sonochemistry and Sonoluminescence. NATO ASI Series C, Vol. 524. Kluwer Publishers, Dordrecht, the Netherlands.

[11] Destaillats, H., Hung, H.M., Hoffmann, M.R., 2000. Degradation of alkylphenol ethoxylate surfactants in water with ultrasonic irradiation. Environ. Sci. Technol., 34(2):311-317.

[12] Di Corcia, A., Capuani, L., Casassa, F., Marcomini, A., Samperi, R., 1999. Fate of linear alkyl benzenesulfonates, coproducts, and their metabolites in sewage treatment plants and receiving river waters. Environ. Sci. Technol., 33(22):4119-4125.

[13] Eganhouse, R.P., Kaplan, I.R., 1982. Extractable organic matter in municipal wastewaters. Hydrocarbons: molecular characterization. Environ. Sci. Technol., 16(9):541-883.

[14] Field, J.A., Field, T.M., Poiger, T., Siegrist, H., Giger, W., 1995. Fate of secondary alkane sulfonate surfactants during municipal wastewater treatment. Water Res., 29(5):1301-1307.

[15] Gong, C., Hart, D.P., 1998. Ultrasound induced cavitation and sonochemical yields. JASA, 104(4):2675-2682.

[16] Jyoti, K.K., Pandit, A.B., 2003. Hybrid cavitation methods for water disinfection: simulation use of chemicals with cavitation. Ultrasonics Sonochemistry, 10(4-5):255-264.

[17] Leighton, T.G., 1994. The Acoustic Bubble. Academic Press, London.

[18] Lin, S.H., Peng, F.C., 1994. Treatment of textile wastewater by electrochemical method. Water Res., 28(2):277-282.

[19] Manousaki, E., Psillakis, E., Kalogerakis, N., Mantzavinos, D., 2004. Degradation of sodium dodecylbenzene sulfonate in water by ultrasonic irradiation. Water Res., 38(17):3751-3759.

[20] Mason, T.J., 1999. Advances in Sonochemistry, Vol. 5. JAI Press, New York.

[21] Mason, T.J., 2003. Sonochemistry and sonoprocessing: the link, the trends and (probably) the future. Ultrasonics Sonochemistry, 10(4-5):175-179.

[22] Mason, T.J., Tiehm, A., 2001. Ultrasound in Environmental Protection. Series Advances in Sonochemistry, Vol. 6, JAI Press, USA.

[23] Mason, T.J., Newman, A.P., Phull, S.S., 1993. Sonochemistry in Water Treatment. BHR Group Conf. Ser. Publ. 2nd International Conference on Advances in Water and Effluent Treatment.

[24] Neppiras, E.A., 1980. Acoustic cavitation. Physics Reports, 61(3):159-251.

[25] Psillakis, E., Mantzavinos, D., Kalogerakis, N., 2004. Monitoring the sonochemical degradation of phthalate esters in water using solid-phase microextraction. Chemosphere, 54(7):849-857.

[26] Scott, M.J., Jones, M.N., 2000. The biodegradation of surfactants in the environment. Biochimica et Biophysica Acta (BBA)-Biomembranes, 1508(1-2):235-251.

[27] Suslick, K.S., Price, G.J., 1999. Applications of ultrasound to materials chemistry. Annu. Rev. Mater. Sci., 29(1):295-326.

[28] Takada, H., Ishiwatari, R., Ogura, N., 1992. Distribution of linear alkylbenzenes and linear alkylbenzene sulphonate in Tokyo Bay sediments. Estuarine, Coastal and Shelf Science, 35(2):141-156.

[29] Thompson, L.H., Doraiswamy, L.K., 1999. Sonochemistry science and engineering. Ind. Eng. Chem. Res., 38(4):1215-1249.

[30] Weavers, L.K., Frim, J., Rathman, J., Pee, G., 2005. Ultrasonic destruction of surfactants: application to industrial wastewaters. Water Environ. Res., 77(3):259-265.

[31] Yim, B., Okano, H., Nagata, Y., Nishimura, R., Maeda, Y., 2002. Sonolysis of surfactants in aqueous solution: an accumulation of solute in the interfacial region of the cavitation bubbles. Ultrasonics Sonochemistry, 9(4):209-213.

[32] Zeni, C., Caligiuri, A., 1992. Morphological and ultra structural changes induced by sublethal concentrations of an anionic detergent on Ictalvrus species barbell taste buds. Microbios, 69:41-52.

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