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Journal of Zhejiang University SCIENCE B 2005 Vol.6 No.1 P.69-73


Microcalorimetric study on host-guest complexation of naphtho-15-crown-5 with four ions of alkaline earth metal

Author(s):  SONG Ming-zhi, ZHU Lan-ying, GAO Xi-ke, DOU Jian-min, SUN De-zhi

Affiliation(s):  Department of Chemistry, Liaocheng University, Liaocheng 252059, China

Corresponding email(s):   sundezhisdz@163.com

Key Words:  Microcalorimetry, Host-guest complexation, Naphtho-15-crown-5, Alkaline earth metal, Molecular recognition

SONG Ming-zhi, ZHU Lan-ying, GAO Xi-ke, DOU Jian-min, SUN De-zhi. Microcalorimetric study on host-guest complexation of naphtho-15-crown-5 with four ions of alkaline earth metal[J]. Journal of Zhejiang University Science B, 2005, 6(1): 69-73.

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author="SONG Ming-zhi, ZHU Lan-ying, GAO Xi-ke, DOU Jian-min, SUN De-zhi",
journal="Journal of Zhejiang University Science B",
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%0 Journal Article
%T Microcalorimetric study on host-guest complexation of naphtho-15-crown-5 with four ions of alkaline earth metal
%A SONG Ming-zhi
%A ZHU Lan-ying
%A GAO Xi-ke
%A DOU Jian-min
%A SUN De-zhi
%J Journal of Zhejiang University SCIENCE B
%V 6
%N 1
%P 69-73
%@ 1673-1581
%D 2005
%I Zhejiang University Press & Springer
%DOI 10.1631/jzus.2005.B0069

T1 - Microcalorimetric study on host-guest complexation of naphtho-15-crown-5 with four ions of alkaline earth metal
A1 - SONG Ming-zhi
A1 - ZHU Lan-ying
A1 - GAO Xi-ke
A1 - DOU Jian-min
A1 - SUN De-zhi
J0 - Journal of Zhejiang University Science B
VL - 6
IS - 1
SP - 69
EP - 73
%@ 1673-1581
Y1 - 2005
PB - Zhejiang University Press & Springer
ER -
DOI - 10.1631/jzus.2005.B0069

Thermodynamic parameters of complexation of naphto-15-crown-5 with four alkaline earth ions in aqueous media was determined using titration microcalorimetry at 298.15 K. The stability of the complexes, thermal effect and entropy effect of the complexation is discussed on the basis of the guest ions structure and the solvent effect. The stability constants tendency to vary with ion radius was interpreted. Complex of naphtha-15-crown-5 with calcium ion is very stable due to the synergism of static electric interaction and size selectivity between the host and the guest.

Darkslateblue:Affiliate; Royal Blue:Author; Turquoise:Article


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